CAJ | 학술논문

建立了土壤中酞酸酯类的加速溶剂萃取（ASE）―气相色谱―质谱（GC-MS）测定方法。通过对萃取溶剂和层析柱的优化选择,得出优化萃取条件。同时,实验过程中采用铬酸洗液对实验器皿进行清洗,有效控制了环境中酞酸酯对样品的污染。该优化方法结果显示：平均加标回收率为89.5%～106.0%,相对标准偏差为1.5%～5.8%,检出限为0.01～0.09 ng/g。方法具有空白低、回收率高、纯化效果好、灵敏度高的特点,具有很好的应用价值。
건립료토양중태산지류적가속용제췌취（ASE）―기상색보―질보（GC-MS）측정방법。통과대췌취용제화층석주적우화선택,득출우화췌취조건。동시,실험과정중채용락산세액대실험기명진행청세,유효공제료배경중태산지대양품적오염。해우화방법결과현시：평균가표회수솔위89.5%～106.0%,상대표준편차위1.5%～5.8%,검출한위0.01～0.09 ng/g。방법구유공백저、회수솔고、순화효과호、령민도고적특점,구유흔호적응용개치。
A method for the determination of phthalates in soil has been established by accelerated solvent extraction（ASE） coupled with gas chromatography-mass spectrometry（GC/MS）.The optimal conditions were determined by selecting the best solvent and chromatography column.Meanwhile,the disturbance of phthalates in natural environment has been controlled effectively by washing experimental vessels with chromium acid.The result demonstrated the recoveries of the six phthalates were between 89.5% and 106.0%.The relative standard deviations were between 1.5% and 5.8%.The detect limits were between 0.01 ng/g and 0.09 ng/g.The method has the characters of low blank,high recovery,good purification,sensitive and a high application value.