中国有色金属学报(英文版)
中國有色金屬學報(英文版)
중국유색금속학보(영문판)
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
2012年
6期
1412-1417
,共6页
余琨%李少君%陈立三%赵为上%李鹏飞
餘琨%李少君%陳立三%趙為上%李鵬飛
여곤%리소군%진립삼%조위상%리붕비
硅铝合金%快速凝固%热性能%电子封装材料
硅鋁閤金%快速凝固%熱性能%電子封裝材料
규려합금%쾌속응고%열성능%전자봉장재료
Si-Al alloy%rapid solidification%thermal properties%electronic packaging application
采用快速凝固制粉技术和粉末热压烧结技术制备55%Si-Al,70%Si-Al和90%Si-Al 3种过共晶含量的硅铝合金.结果表明:雾化沉积是制备过共晶硅铝合金的有效的快速凝固工艺,采用该工艺获得的快速凝固硅铝合金粉末的尺寸小于50 μm.快速凝固的硅铝合金粉末经过550°C和700 MPa热压后,获得3种不同成分合金试样的相对密度分别为99.4%,99.2%和94.4%.作为电子封装材料,3种试样的热导率、热膨胀系数和电导率都可以满足应用要求.55%Si-Al合金的热膨胀系数随温度的变化最剧烈,但是该合金具有较好的热导率.90%Si-Al合金的热膨胀系数较小,但是其热导率最差,小于100 W/(m·K).70%Si-Al合金具备热沉材料所应具备的优良的热导率和热膨胀系数的综合性能.
採用快速凝固製粉技術和粉末熱壓燒結技術製備55%Si-Al,70%Si-Al和90%Si-Al 3種過共晶含量的硅鋁閤金.結果錶明:霧化沉積是製備過共晶硅鋁閤金的有效的快速凝固工藝,採用該工藝穫得的快速凝固硅鋁閤金粉末的呎吋小于50 μm.快速凝固的硅鋁閤金粉末經過550°C和700 MPa熱壓後,穫得3種不同成分閤金試樣的相對密度分彆為99.4%,99.2%和94.4%.作為電子封裝材料,3種試樣的熱導率、熱膨脹繫數和電導率都可以滿足應用要求.55%Si-Al閤金的熱膨脹繫數隨溫度的變化最劇烈,但是該閤金具有較好的熱導率.90%Si-Al閤金的熱膨脹繫數較小,但是其熱導率最差,小于100 W/(m·K).70%Si-Al閤金具備熱沉材料所應具備的優良的熱導率和熱膨脹繫數的綜閤性能.
채용쾌속응고제분기술화분말열압소결기술제비55%Si-Al,70%Si-Al화90%Si-Al 3충과공정함량적규려합금.결과표명:무화침적시제비과공정규려합금적유효적쾌속응고공예,채용해공예획득적쾌속응고규려합금분말적척촌소우50 μm.쾌속응고적규려합금분말경과550°C화700 MPa열압후,획득3충불동성분합금시양적상대밀도분별위99.4%,99.2%화94.4%.작위전자봉장재료,3충시양적열도솔、열팽창계수화전도솔도가이만족응용요구.55%Si-Al합금적열팽창계수수온도적변화최극렬,단시해합금구유교호적열도솔.90%Si-Al합금적열팽창계수교소,단시기열도솔최차,소우100 W/(m·K).70%Si-Al합금구비열침재료소응구비적우량적열도솔화열팽창계수적종합성능.
The rapid solidified process and hot press method were performed to produce three hypereutectic 55%Si-Al,70%Si-Al and 90%Si-Al alloys for heat dissipation materials.The results show that the atomization is an effective rapid solidified method to produce the Si-Al alloy and the size of atomized Si-Al alloy powder is less than 50 μm.The rapid solidified Si-Al alloy powder were hot pressed at 550 °C with the pressure of 700 MPa to obtain the relative densities of 99.4%,99.2% and 94.4% for 55%Si-Al,70%Si-Al and 90%Si-Al alloys,respectively.The typical physical properties,such as the thermal conductivity,coefficient of thermal expansion (CTE) and electrical conductivity of rapid solidified Si-Al alloys are acceptable as a heat dissipation material for many semiconductor devices.The 55%Si-Al alloy changes greatly (CTE) with the increase of temperature but obtains a good thermal conductivity.The CTE of 90%Si-Al alloy matches with the silicon very well but its thermal conductivity value is less than 100 W/(m·K).Therefore,the 70%Si-Al alloy possesses the best comprehensive properties of CTE and thermal conductivity for using as the heat sink materials.