无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2010年
5期
879-884
,共6页
磷酸氢钙%硅酸三钙%骨水泥
燐痠氫鈣%硅痠三鈣%骨水泥
린산경개%규산삼개%골수니
dicaleium phosphate dihydrate%tricaleium silicate%bone cement
本文将磷酸氢钙(CaHPO4·2H2O,DCPD)添加到硅酸三钙(Ca3SiO5,C3S)骨水泥中,采用X射线衍射(XRD),扫描电镜(SEM),万能力学测试机等手段对不同添加量的骨水泥进行表征,考察添加DCPD对硅酸三钙骨水泥性能的影响.实验表明,C3S材料中添加10%DCPD有着优于单纯C3S骨水泥的水化性能,骨水泥的初凝时间从92 min缩短到80 min;添加20%~30%DCPD能提高材料的短期力学强度,可以实现其短期抗压强度的优化;添加30%~40%DCPD的材料有着优良的生物活性与适中的可降解性能.结果表明,通过添加DCPD优化C3S水泥的性能.对各种不同性能具有DCPD添加量的依赖性.通过进一步优化DCPD添加量,将可能获得优良的生物活性骨缺陷填充材料.
本文將燐痠氫鈣(CaHPO4·2H2O,DCPD)添加到硅痠三鈣(Ca3SiO5,C3S)骨水泥中,採用X射線衍射(XRD),掃描電鏡(SEM),萬能力學測試機等手段對不同添加量的骨水泥進行錶徵,攷察添加DCPD對硅痠三鈣骨水泥性能的影響.實驗錶明,C3S材料中添加10%DCPD有著優于單純C3S骨水泥的水化性能,骨水泥的初凝時間從92 min縮短到80 min;添加20%~30%DCPD能提高材料的短期力學彊度,可以實現其短期抗壓彊度的優化;添加30%~40%DCPD的材料有著優良的生物活性與適中的可降解性能.結果錶明,通過添加DCPD優化C3S水泥的性能.對各種不同性能具有DCPD添加量的依賴性.通過進一步優化DCPD添加量,將可能穫得優良的生物活性骨缺陷填充材料.
본문장린산경개(CaHPO4·2H2O,DCPD)첨가도규산삼개(Ca3SiO5,C3S)골수니중,채용X사선연사(XRD),소묘전경(SEM),만능역학측시궤등수단대불동첨가량적골수니진행표정,고찰첨가DCPD대규산삼개골수니성능적영향.실험표명,C3S재료중첨가10%DCPD유착우우단순C3S골수니적수화성능,골수니적초응시간종92 min축단도80 min;첨가20%~30%DCPD능제고재료적단기역학강도,가이실현기단기항압강도적우화;첨가30%~40%DCPD적재료유착우량적생물활성여괄중적가강해성능.결과표명,통과첨가DCPD우화C3S수니적성능.대각충불동성능구유DCPD첨가량적의뢰성.통과진일보우화DCPD첨가량,장가능획득우량적생물활성골결함전충재료.
Dicalcium phosphate dihydrate (DCPD) was added into C3S bone cements.The cements were characterized with XRD,SEM,and mechanical test to investigate the effect of DCPD.The experiment showed that Ca3SiO5 bone cements added with 10% DCPD had better hydraulic properties than pure C3S bone cement and its initial setting time was reduced from 92 to 80 minutes.The short-term mechanical strengths of the materials were promoted by adding with 20%~30%DCPD,and the short-term mechanical strength could be optimized.The materials have better bioactivities and moderate degradability by adding with 30%~40% DCPD.The results demonstrated that the properties of C3S cement could be improved by the addition of DCPD,and the different properties of C3S cement could be regulated by the amount of DCPD addition.It is expected to obtain excellent bioactive bone defect filling materials by optimizing the ratio of DCPD in the cement.