CAJ | 학술논문

合成了2-[1-(3-叔丁基)吡唑基甲基]吡啶(CH2(Py)(3-ButPz)),并研究了羰基钼(钨)与该配体及其类似物2-(1-吡唑基甲基)吡啶(CH2(Py)(Pz))和2-[1-(3,5-二甲基)吡唑基甲基]吡啶(CH2(Py)(3,5-Me2Pz))的反应,合成了6个含双齿螫合的2-(1-吡唑基甲基)吡啶类配体的四羰基金属衍生物CH2(Py)(3 -ButPz) M(CO)4,CH2(Py)(Pz)M(CO)4和CH2(Py)(3,5-Me2Pz) M(CO)4(M=Mo或W).当用SnCl4处理CH2(Py)(3,5-Me2Pz) M(CO)4时,Sn-Cl键对金属中心发生氧化加成得到2个杂双核金属有机化合物CH2(Py)(3,5-Me2Pz) M(CO)3(Cl)SnCl3.所有新化合物均通过了红外和核磁的表征,CH2(Py)(3-ButPz)W(CO)4和CH2(Py)(3,5-Me2Pz)W(CO)3(Cl)SnCl3的结构还得到了X-射线单晶衍射的确证.用循环伏安法测定了四羰基金属衍生物的电化学性质.
합성료2-[1-(3-숙정기)필서기갑기]필정(CH2(Py)(3-ButPz)),병연구료탄기목(오)여해배체급기유사물2-(1-필서기갑기)필정(CH2(Py)(Pz))화2-[1-(3,5-이갑기)필서기갑기]필정(CH2(Py)(3,5-Me2Pz))적반응,합성료6개함쌍치석합적2-(1-필서기갑기)필정류배체적사탄기금속연생물CH2(Py)(3 -ButPz) M(CO)4,CH2(Py)(Pz)M(CO)4화CH2(Py)(3,5-Me2Pz) M(CO)4(M=Mo혹W).당용SnCl4처리CH2(Py)(3,5-Me2Pz) M(CO)4시,Sn-Cl건대금속중심발생양화가성득도2개잡쌍핵금속유궤화합물CH2(Py)(3,5-Me2Pz) M(CO)3(Cl)SnCl3.소유신화합물균통과료홍외화핵자적표정,CH2(Py)(3-ButPz)W(CO)4화CH2(Py)(3,5-Me2Pz)W(CO)3(Cl)SnCl3적결구환득도료X-사선단정연사적학증.용순배복안법측정료사탄기금속연생물적전화학성질.
2-(3-tert-Butylpyrazol- l-ylmethyl)pyridine (CH2(Py) (3-ButPz),Py=2-pyridyl and Pz =pyrazol- 1-yl) has been prepared by the reaction of 3-tert-butylpyrazole and 2-chloromethylpyridine-HCl under basic conditions.Reaction of CH2(Py)(3-ButPz) and its analogs,namely CH2(Py)(Pz) and CH2(Py)(3,5-Me2Pz),with M(CO)6 (M=Mo or W) has been investigated,which yields six bidentate chelating complexes CH2(Py)(3-ButPz)M(CO)4,CH2(Py)(Pz)M (CO)4 and CH2(Py)(3,5-Me2Pz)M(CO)4.Treatment of CH2(Py)(3,5-Me2Pz)M(CO)4 with SnCl4 gives beterobimetallic complexes CH2(Py)(3,5-Me2Pz)M(CO)3(Cl)SnCl3.These newly synthesized complexes have been characterized by IR and NMR spectroscopy,and the structures of CH2(Py)(3-ButPz)W(CO)4 and CH2(Py)(3,5-Me2Pz)W(CO)3(Cl)SnCl3have been further confirmed by X-ray crystal diffraction.The electrochemical behavior of CH2 (Py)(3-ButPz)M(CO)4,CH2(Py)(Pz)M(CO)4 and CH2(Py)(3,5-Me2Pz)M(CO)4 has been investigated by cyclic voltammetry.CCDC:820993,6; 820994,8.