温州师范学院学报
溫州師範學院學報
온주사범학원학보
JOURNAL OF WENZHOU TEACHERS COLLEGE
2003年
5期
25-29
,共5页
配位聚合物%对苯二甲酸%钴(Ⅱ)%三乙烯二胺%网络结构
配位聚閤物%對苯二甲痠%鈷(Ⅱ)%三乙烯二胺%網絡結構
배위취합물%대분이갑산%고(Ⅱ)%삼을희이알%망락결구
利用对苯二甲酸(H2BDC),三乙烯二胺(TED),CoCl2·6H2O为原料,采用溶液扩散混合法合成了三个新的配合物[Co(BDC)(0.5TED)]n(2nDMF)1.5nH2O)(I),[Co(BDC)(TED)]n(nDMF)(1.5nH2O)(II),[Ni(BDC)(0.5TED)]n(2nDMF)(1.5nH2O)(Ⅲ),并对其进行了元素分析、红外光谱分析和热重分析,结果表明三个化合物是三维网络结构的配位聚合物.
利用對苯二甲痠(H2BDC),三乙烯二胺(TED),CoCl2·6H2O為原料,採用溶液擴散混閤法閤成瞭三箇新的配閤物[Co(BDC)(0.5TED)]n(2nDMF)1.5nH2O)(I),[Co(BDC)(TED)]n(nDMF)(1.5nH2O)(II),[Ni(BDC)(0.5TED)]n(2nDMF)(1.5nH2O)(Ⅲ),併對其進行瞭元素分析、紅外光譜分析和熱重分析,結果錶明三箇化閤物是三維網絡結構的配位聚閤物.
이용대분이갑산(H2BDC),삼을희이알(TED),CoCl2·6H2O위원료,채용용액확산혼합법합성료삼개신적배합물[Co(BDC)(0.5TED)]n(2nDMF)1.5nH2O)(I),[Co(BDC)(TED)]n(nDMF)(1.5nH2O)(II),[Ni(BDC)(0.5TED)]n(2nDMF)(1.5nH2O)(Ⅲ),병대기진행료원소분석、홍외광보분석화열중분석,결과표명삼개화합물시삼유망락결구적배위취합물.
