上海塑料
上海塑料
상해소료
SHANGHAI PLASTICS
2011年
2期
32-35
,共4页
匡俊杰%杨其%游华燕%池晓明%诸泉%蒋文真
劻俊傑%楊其%遊華燕%池曉明%諸泉%蔣文真
광준걸%양기%유화연%지효명%제천%장문진
聚丙烯%K树脂%纳米CaCO3%SBS%增容
聚丙烯%K樹脂%納米CaCO3%SBS%增容
취병희%K수지%납미CaCO3%SBS%증용
polypropylene%K-resin%nano-CaCO3%SBS%compatibilization
研究了纳米CaCO3和SBS分别添加和复配添加对PP/K树脂(70/30)共混体系相容性的影响。结果表明:纳米CaCO3的质量分数为5.7%时,体系的分散相尺寸降低,分布均匀性改善,有一定的增容效果;当其质量分数为9.1%时,体系的相容性保持不变;SBS的增容效果与纳米CaCO3的类似。纳米CaCO3和SBS先双辊混炼后再复配填充PP/K树脂(70/30)体系,其质量分数为9.1%时,改变纳米CaCO3/SBS的配比,体系的相容性变化不大;纳米CaCO3与SBS复配填充PP/K树脂(70/30)体系的缺口冲击强度比纳米CaCO3或SBS单独填充体系的都有明显提高,但拉伸强度变化不大。
研究瞭納米CaCO3和SBS分彆添加和複配添加對PP/K樹脂(70/30)共混體繫相容性的影響。結果錶明:納米CaCO3的質量分數為5.7%時,體繫的分散相呎吋降低,分佈均勻性改善,有一定的增容效果;噹其質量分數為9.1%時,體繫的相容性保持不變;SBS的增容效果與納米CaCO3的類似。納米CaCO3和SBS先雙輥混煉後再複配填充PP/K樹脂(70/30)體繫,其質量分數為9.1%時,改變納米CaCO3/SBS的配比,體繫的相容性變化不大;納米CaCO3與SBS複配填充PP/K樹脂(70/30)體繫的缺口遲擊彊度比納米CaCO3或SBS單獨填充體繫的都有明顯提高,但拉伸彊度變化不大。
연구료납미CaCO3화SBS분별첨가화복배첨가대PP/K수지(70/30)공혼체계상용성적영향。결과표명:납미CaCO3적질량분수위5.7%시,체계적분산상척촌강저,분포균균성개선,유일정적증용효과;당기질량분수위9.1%시,체계적상용성보지불변;SBS적증용효과여납미CaCO3적유사。납미CaCO3화SBS선쌍곤혼련후재복배전충PP/K수지(70/30)체계,기질량분수위9.1%시,개변납미CaCO3/SBS적배비,체계적상용성변화불대;납미CaCO3여SBS복배전충PP/K수지(70/30)체계적결구충격강도비납미CaCO3혹SBS단독전충체계적도유명현제고,단랍신강도변화불대。
The effects on compatibility of PP/K-resin(70/30) blends filled with nano-CaCO3 or SBS respectively or their assembling were investigated.The research showed that when the mass fraction of nano-CaCO3 was 5.7%,the size of dispersed phase decreased and the distribution improved,increasing the addition to 9.1%,the compatibilization had little change,which was similar to SBS.Adding 9.1% of nano-CaCO3/SBS which was fixed firstly,varying the ratio of nano-CaCO3 to SBS,the compatibilization of systems changed little.Comparing to nano-CaCO3 or SBS filled systems solely,the izod impact strength of nano-CaCO3 /SBS filled systems had notable increase,and the tensile strength changed little.