生物质化学工程
生物質化學工程
생물질화학공정
BIOMASS CHEMICAL ENGINEERING
2011年
5期
11-16
,共6页
李辉勇%金密%魏琴琴%李志光
李輝勇%金密%魏琴琴%李誌光
리휘용%금밀%위금금%리지광
弱碱性%过氧化氢%稻草%预处理%酶水解
弱堿性%過氧化氫%稻草%預處理%酶水解
약감성%과양화경%도초%예처리%매수해
mild alkaline%peroxide%rice straw%pretreatment%enzymatic hydrolysis
为了提高稻草秸秆的酶解糖化率,对稻草秸秆弱碱性过氧化预处理条件进行了优化。结果表明:弱碱性过氧化预处理降低了稻草秸秆中木质素的含量,提高了纤维素的含量。最优预处理条件为温度40℃,时间24 h,H2O2质量分数为2.0%,在此条件下稻草秸秆的酶解糖化率达到了83.23%,而在相同酶解条件下,预处理温度30℃、时间24 h、2.0%NaOH处理后稻草秸秆的酶解糖化率为70.38%。弱碱性过氧化预处理稻草秸秆的糖化率明显高于碱性预处理稻草秸秆的糖化率。同时试验结果表明,木质素的除去率与H2O2质量分数有关。当H2O2质量分数大于2.0%后,H2 O2对木质素的除去选择性降低,木质素的除去率基本保持不变,却增加了半纤维素的损失。
為瞭提高稻草秸稈的酶解糖化率,對稻草秸稈弱堿性過氧化預處理條件進行瞭優化。結果錶明:弱堿性過氧化預處理降低瞭稻草秸稈中木質素的含量,提高瞭纖維素的含量。最優預處理條件為溫度40℃,時間24 h,H2O2質量分數為2.0%,在此條件下稻草秸稈的酶解糖化率達到瞭83.23%,而在相同酶解條件下,預處理溫度30℃、時間24 h、2.0%NaOH處理後稻草秸稈的酶解糖化率為70.38%。弱堿性過氧化預處理稻草秸稈的糖化率明顯高于堿性預處理稻草秸稈的糖化率。同時試驗結果錶明,木質素的除去率與H2O2質量分數有關。噹H2O2質量分數大于2.0%後,H2 O2對木質素的除去選擇性降低,木質素的除去率基本保持不變,卻增加瞭半纖維素的損失。
위료제고도초갈간적매해당화솔,대도초갈간약감성과양화예처리조건진행료우화。결과표명:약감성과양화예처리강저료도초갈간중목질소적함량,제고료섬유소적함량。최우예처리조건위온도40℃,시간24 h,H2O2질량분수위2.0%,재차조건하도초갈간적매해당화솔체도료83.23%,이재상동매해조건하,예처리온도30℃、시간24 h、2.0%NaOH처리후도초갈간적매해당화솔위70.38%。약감성과양화예처리도초갈간적당화솔명현고우감성예처리도초갈간적당화솔。동시시험결과표명,목질소적제거솔여H2O2질량분수유관。당H2O2질량분수대우2.0%후,H2 O2대목질소적제거선택성강저,목질소적제거솔기본보지불변,각증가료반섬유소적손실。
Mild alkaline peroxide pretreatment conditions for rice straw were optimized with a view to increase the ratio of enzymatic saccharification.The results showed that the mild alkaline peroxide pretreatment reduced the content of lignin and increased the content of cellulose of rice straw.The optimal pretreament conditions were as follows : temperature 40 ℃,reaction time 24 h,hydrogen peroxide 2.0 %.Under the optimal conditions,the enzymatic saccharification ratio of the mild alkaline peroxide pretreated rice straw was 83.23 %.The enzymatic saccharification ratio of rice straw pretreated by the alkaline with 2.0 % NaOH,temperature 30 ℃,time 24 h was 70.38 %.The enzymatic saccharification ratio of the mild alkaline peroxide pretreated rice straw is higher evidently than that of the alkaline pretreated rice straw.The results also showed that the removal efficiency of lignin was affected by the mass fraction of hydrogen peroxide.When the mass fraction of hydrogen peroxide is greater than 2.0 %,the selectivity of lignin removal is decreased.Lignin removal remains unchanged,but the loss ratio of hemicelluloses is increased.