CAJ | 학술논문

利用水热反应合成了一种新的二维双层蜂窝状锌配合物{[Zn2(atz)3(N3)]· H20}n (1)(atz=5-氨基四氮唑),并用元素分析,红外光谱和X-射线单晶衍射对其结构进行了表征,该配合物属单斜晶系,C2/m空间群,晶胞参数为:a=1.0397 (2) nm,b= 1.792 7(4)nm,c=1.109 2(2) nm,V=1.8870(7) nm3,Z=4.该锌配合物是由N3-和原位合成的5-氨基四氮唑阴离子构成,拓扑分析表明该化合物显示出独特的4-连接六边形的蜂窝双层结构.同时还测定了该化合物的热稳定性及荧光性质.
이용수열반응합성료일충신적이유쌍층봉와상자배합물{[Zn2(atz)3(N3)]· H20}n (1)(atz=5-안기사담서),병용원소분석,홍외광보화X-사선단정연사대기결구진행료표정,해배합물속단사정계,C2/m공간군,정포삼수위:a=1.0397 (2) nm,b= 1.792 7(4)nm,c=1.109 2(2) nm,V=1.8870(7) nm3,Z=4.해자배합물시유N3-화원위합성적5-안기사담서음리자구성,탁복분석표명해화합물현시출독특적4-련접륙변형적봉와쌍층결구.동시환측정료해화합물적열은정성급형광성질.
A new 2D bilayer honeycomb zinc complex of {[Zn2(atz)3(N3)]· H2O}n (1) (atz=5-amino-tetrazolate),hasbeen synthesized under the hydrothermal condition and characterized by elemental analysis,IR spectroscopy andsingle-crystal X-ray diffraction.The crystal structure of 1 is of monoclinic,space group C2/m with a=1.039 7(2)nm,b=1.7927(4) nm,c=1.1092(2) nm,V=1.8870(7) nm3,Z=4.Complex 1 is built from N3- anion and in-situgenerated 5-amino-tetrazolate ligand.The topological net of 1 shows a unique four-connected hexagonal bilayer“hcb” topology (honeycomb network).Thermal stability and luminescent property of the complex have also beeninvestigated.CCDC:722571.