中山大学学报(自然科学版)
中山大學學報(自然科學版)
중산대학학보(자연과학판)
ACTA SCIENTIARUM NATURALIUM UNIVERSITATIS SUNYATSENI
2007年
z1期
67-68
,共2页
王仲妮%孟琳%周武%丁兆云%李干佐%张高勇
王仲妮%孟琳%週武%丁兆雲%李榦佐%張高勇
왕중니%맹림%주무%정조운%리간좌%장고용
离子液体%Brij97%层状液晶
離子液體%Brij97%層狀液晶
리자액체%Brij97%층상액정
ionic liquid%Brij 97%lamellar liquid crystals
利用小角X射线散射和小幅振荡实验研究了Brij 97/H2O/ bmim-BF4 和 Brij 97/H2O / bmim-PF6 体系层状液晶的微观结构和动态流变性质.结果表明两层状液晶体系分别表现gel-like 和fluid-like 的动态流变行为,而且 bmim-PF6 和 bmim-BF4增溶在液晶结构的不同位置.
利用小角X射線散射和小幅振盪實驗研究瞭Brij 97/H2O/ bmim-BF4 和 Brij 97/H2O / bmim-PF6 體繫層狀液晶的微觀結構和動態流變性質.結果錶明兩層狀液晶體繫分彆錶現gel-like 和fluid-like 的動態流變行為,而且 bmim-PF6 和 bmim-BF4增溶在液晶結構的不同位置.
이용소각X사선산사화소폭진탕실험연구료Brij 97/H2O/ bmim-BF4 화 Brij 97/H2O / bmim-PF6 체계층상액정적미관결구화동태류변성질.결과표명량층상액정체계분별표현gel-like 화fluid-like 적동태류변행위,이차 bmim-PF6 화 bmim-BF4증용재액정결구적불동위치.
Microstructure and dynamic rheological properties of lamellar liquid crystals formed in Brij 97/water/ bmim-BF4 and Brij 97/water/ bmim-PF6 systems were investigated by means of SAXS and small amplitude oscillatory shear measurements. It is shown that two systems exhibit gel-like and fluid-like rheograms respectively, along with the different locations of bmim-PF6 and bmim-BF4 penetrating through the lamellar phase.