CAJ | 학술논문

采用γ射线辐射法在非水体系中成功地合成出具有一定形状的硫化镉纳米粒子。分别以无水乙醇及体积比为1:1的无水乙醇与苯的混合溶液为溶剂，以二硫化碳和单质硫为硫源。当辐照时，产生的溶剂化电子把二硫化碳或单质硫还原成S2-，S2-迅速与Cd2+形成CdS沉淀。研究发现，不同的溶剂和反应物对产物的晶相、粒径存在着影响。
채용γ사선복사법재비수체계중성공지합성출구유일정형상적류화력납미입자。분별이무수을순급체적비위1:1적무수을순여분적혼합용액위용제，이이류화탄화단질류위류원。당복조시，산생적용제화전자파이류화탄혹단질류환원성S2-，S2-신속여Cd2+형성CdS침정。연구발현，불동적용제화반응물대산물적정상、립경존재착영향。
Cadmium sulfide nano-particles with certain shapes have been sucessfully synthesized via γ-ray irradiation in the non-water system. Absolute ethanol and a mixed solution of ethanol and benzene with the volume ratio of 1:1 are used as the solvents, and carbon disulfide and sulfur powders as the sulfur ions source, respectively. When the solutions are irradiated, carbon disulfide or sulfur element is reduced into S2- by the produced solvational electrons. CdS is precipitated through the combining reaction of S2- and Cd2+ ions. The investigation reveals that the phases and sizes of the products are affected by different solvents and sulfur ions sources.