天然气化工
天然氣化工
천연기화공
NATURAL GAS CHEMICAL INDUSTRY
2010年
2期
18-21,27
,共5页
正丁烷%催化裂解%催化剂%乙烯%丙烯
正丁烷%催化裂解%催化劑%乙烯%丙烯
정정완%최화렬해%최화제%을희%병희
n-butane%catalytic cracking%FCC eatalyst%ethylene%propylene
在固定床微型反应器装置上,对正丁烷在5种不同催化裂化催化剂上的裂解反应过程进行了考察.结果表明,其中ZRP.1催化剂的乙烯和丙烯收率最高.进一步考察了在ZRP-1催化剂上不同的反应条件对于正丁烷转化率和乙烯与丙烯的收率及选择性的影响.结果表明,正丁烷催化裂解的最佳工艺条件为:反应温度640℃,催化剂装量0.5g,气体流量0.003L/min.在该条件下乙烯和丙烯的收率分别为19.6%和17.8%.
在固定床微型反應器裝置上,對正丁烷在5種不同催化裂化催化劑上的裂解反應過程進行瞭攷察.結果錶明,其中ZRP.1催化劑的乙烯和丙烯收率最高.進一步攷察瞭在ZRP-1催化劑上不同的反應條件對于正丁烷轉化率和乙烯與丙烯的收率及選擇性的影響.結果錶明,正丁烷催化裂解的最佳工藝條件為:反應溫度640℃,催化劑裝量0.5g,氣體流量0.003L/min.在該條件下乙烯和丙烯的收率分彆為19.6%和17.8%.
재고정상미형반응기장치상,대정정완재5충불동최화열화최화제상적렬해반응과정진행료고찰.결과표명,기중ZRP.1최화제적을희화병희수솔최고.진일보고찰료재ZRP-1최화제상불동적반응조건대우정정완전화솔화을희여병희적수솔급선택성적영향.결과표명,정정완최화렬해적최가공예조건위:반응온도640℃,최화제장량0.5g,기체류량0.003L/min.재해조건하을희화병희적수솔분별위19.6%화17.8%.
Effects of five different FCC catalysts on the reaction of n-butane cracking to ethylene and prepylene were investigated in a micro fixed-bed reactor,and it was found ZRP-1 catalyst had the highest ethylene and propylene yields.The reaction eonditions for n-butane cracking over ZRP-1 catalyst were further studied.and the results showed that the optimum operation parameters were as follows:reaction temperature 640℃,catalyst 0.5g,feed gas flux O.03L/min.Under the optimized conditions,the yields of ethylene and propylene were 19.6%and 17.8%.respectively.