高等学校化学学报
高等學校化學學報
고등학교화학학보
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES
2001年
1期
31-33
,共3页
烷基钴配合物%环糊精%超分子
烷基鈷配閤物%環糊精%超分子
완기고배합물%배호정%초분자
Two long carbon chain alkyl (aqua) Costa-type organocobalt complexes (R=C6H13 and C8H17) have been synthesized for the first time and characterized by elemental analysis,UV-Vis and 1H NMR.Their inclusion behavior withβ-cyclodextrin was studied by 1H NMR methods.It was indicated that in aqueous solution supramolecular adducts have been formed,in which the alkyl groups of the guests were included into the cavity of β-CD.Cyclic voltammetry methods was also used to study the electrochemical properties of organocobalt complexes in the absence and presence of β-CD.
