石油与天然气化工
石油與天然氣化工
석유여천연기화공
CHEMICAL ENGINEERING OF OIL AND GAS
2009年
5期
453-455
,共3页
马其金%杨眉%张启根%苏银华%谢显涛
馬其金%楊眉%張啟根%囌銀華%謝顯濤
마기금%양미%장계근%소은화%사현도
钻井液%硫化氢%除硫剂%缓蚀剂%钻井液流变性
鑽井液%硫化氫%除硫劑%緩蝕劑%鑽井液流變性
찬정액%류화경%제류제%완식제%찬정액류변성
drilling fluid%hydrogen sulphide%sulphide scavenger%corrosion inhibitor%drilling fluid rheological property
评价了试验室自制的亚铁离子络合物型除硫剂,该除硫剂是以二价铁离子与碳水化合物衍生物复合而成的,在水基钻井液中能高度溶解,并且在pH值为12的环境下不会沉淀,在钻井液体系pH值为9时除硫效率最高,可以达到98.6%左右.在60℃环境中除硫剂与硫化氢比值为1.4时,对钻具的缓蚀率最高为71.23%,,可以显著缓解H2S对钻具的腐蚀.该除硫剂与常用的聚磺钻井液具有良好的配伍性,对钻井液的流变性和失水都没有明显的影响.
評價瞭試驗室自製的亞鐵離子絡閤物型除硫劑,該除硫劑是以二價鐵離子與碳水化閤物衍生物複閤而成的,在水基鑽井液中能高度溶解,併且在pH值為12的環境下不會沉澱,在鑽井液體繫pH值為9時除硫效率最高,可以達到98.6%左右.在60℃環境中除硫劑與硫化氫比值為1.4時,對鑽具的緩蝕率最高為71.23%,,可以顯著緩解H2S對鑽具的腐蝕.該除硫劑與常用的聚磺鑽井液具有良好的配伍性,對鑽井液的流變性和失水都沒有明顯的影響.
평개료시험실자제적아철리자락합물형제류제,해제류제시이이개철리자여탄수화합물연생물복합이성적,재수기찬정액중능고도용해,병차재pH치위12적배경하불회침정,재찬정액체계pH치위9시제류효솔최고,가이체도98.6%좌우.재60℃배경중제류제여류화경비치위1.4시,대찬구적완식솔최고위71.23%,,가이현저완해H2S대찬구적부식.해제류제여상용적취광찬정액구유량호적배오성,대찬정액적류변성화실수도몰유명현적영향.
The performance of the ferric ion complex sulphide scavenger is tested in laboratory. This sulphide scavenger is synthesized by ferrous and derivate of carbohydrates. It is easy dissolved in water-base drilling fluid and cannot subside when the pH value is 12, while the desulphuration efficiency can get as high as 98.6% as the pH value of drilling fluids is 9. Under 70℃, the highest corrosion control efficiency value is 71.23 %, which can remarkably slow down the corrosion rate for drilling rig. The sulphide scavenger is good compatible with poly-sulfonate drilling fluids, and won't obviously affect the rheology and filtration loss of the drilling fluid. The desulfuration has rapid reaction velocity and high reaction effectiveness. It not only prolong the life of drilling rig, but also protect people not be infected by H_2S.