CAJ | 학술논문

通过利用相同的原料但不同的合成过程,本文制备了一个单核镍(Ⅱ)配合物[NiL(H2O)](1),和一个三核镍(Ⅱ)配合物[Ni3L2(μ-CH3COO)2](2),其中L是N,N'-二(4-甲氧基亚水杨基)丙烷-1,3-二-胺(H2L)的二价阴离子.通过元素分析、红外光谱以及X-射线单晶衍射表征了这2个配合物的结构.本文还研究了这2个配合物的热稳定性.
통과이용상동적원료단불동적합성과정,본문제비료일개단핵얼(Ⅱ)배합물[NiL(H2O)](1),화일개삼핵얼(Ⅱ)배합물[Ni3L2(μ-CH3COO)2](2),기중L시N,N'-이(4-갑양기아수양기)병완-1,3-이-알(H2L)적이개음리자.통과원소분석、홍외광보이급X-사선단정연사표정료저2개배합물적결구.본문환연구료저2개배합물적열은정성.
A mononuclear nickel(Ⅱ) complex [NiL(H2O)](1),and a trinuclear nickel(Ⅱ) complex [Ni3L2(μ-CH3COO)2](2),where L is the dianionic form of N,N'-bis(4-methoxysalicylidene)propane-1,3-diamine (H2L),were synthesized from the same starting materials but with different synthetic procedures.The complexes were characterized by elemental analyses,infrared spectroscopy,and X-ray single crystal determination.The thermal stability of the complexes was also studied.CCDC:736566,1; 736567,2.