CAJ | 학술논문

利用水热法合成了一种新型二维配位聚合物Pb(dpq)(bdic)(dpq=二-吡啶-(3,2-d:2′,3′-f)-二氮萘,H_2bdic=丁二酸).通过元素分析、IR、单晶X射线衍射对配合物的结构进行了表征.结果表明:该配合物属于三斜晶系,P-1空间群;晶胞参数a=0.697 8(5) nm,b=0.868 9(6) nm,c=1.395 0(10) nm,α=100.995(8)°,β=100.164(8)°,γ=101.649(8)°,Z=2,V=0.792 6(10) nm~3,R_1=0.084 5,wR_2=0.210 1.标题配合物有较好的热稳定性.此外,该固态配合物在室温下表现出绿色的荧光性质.
이용수열법합성료일충신형이유배위취합물Pb(dpq)(bdic)(dpq=이-필정-(3,2-d:2′,3′-f)-이담내,H_2bdic=정이산).통과원소분석、IR、단정X사선연사대배합물적결구진행료표정.결과표명:해배합물속우삼사정계,P-1공간군;정포삼수a=0.697 8(5) nm,b=0.868 9(6) nm,c=1.395 0(10) nm,α=100.995(8)°,β=100.164(8)°,γ=101.649(8)°,Z=2,V=0.792 6(10) nm~3,R_1=0.084 5,wR_2=0.210 1.표제배합물유교호적열은정성.차외,해고태배합물재실온하표현출록색적형광성질.
A novel 2D coordination polymer Pb(dpq)(bdic) (dpq = dipyrido[3,2-d:2′,3′-f]quinoxaline,H_2bdic =butanedioic acid) has been prepared under hydrothermal reaction and structurally characterized by elemental analyses,IR spectroscopy,and single-crystal X-ray diffraction analysis.The complex belongs to triclinic,space group P-1; a=0.697 8(5) nm,b=0.868 9(6) nm,c=1.395 0(10) nm,a=100.995(8)°,β=100.164(8)°,γ=101.649(8)°,Z=2,V=0.792 6(10) nm~3,R_1=0.084 5,wR_2=0.210 1.The title complex exhibits good thermal stability.Moreover,the title complex exhibits green emission in the solid state at room temperature.