CAJ | 학술논문

草酸酯加氢合成乙二醇过程中负载量为20％的Cu催化剂可以获得较高的乙二醇(EG)收率,但是该催化剂寿命过短的问题限制了其工业应用.本实验主要研究造成该催化剂失活的原因.使用蒸氨法将铜负载在SiO2上,制成用于草酸二乙酯(DEO)加氢的催化剂.运用X射线衍射(XRD)、程序升温还原(TPR)和高分辨率透射电镜(HRTWEM)来表征催化剂.发现铜颗粒以很小的粒径高度分散在新鲜催化剂的表面,而这些颗粒的聚集正是造成催化剂失活的主要原因.结果还表明,Cu0是加氢过程中的主要活性位.
초산지가경합성을이순과정중부재량위20％적Cu최화제가이획득교고적을이순(EG)수솔,단시해최화제수명과단적문제한제료기공업응용.본실험주요연구조성해최화제실활적원인.사용증안법장동부재재SiO2상,제성용우초산이을지(DEO)가경적최화제.운용X사선연사(XRD)、정서승온환원(TPR)화고분변솔투사전경(HRTWEM)래표정최화제.발현동과립이흔소적립경고도분산재신선최화제적표면,이저사과립적취집정시조성최화제실활적주요원인.결과환표명,Cu0시가경과정중적주요활성위.
High yield of ethylene glycol (EG) can be obtainedby using the catalyst with 20％ Cu loading,but the short life of the catalyst blocks its industrial application.This work focuses on the cause of the deactivation behavior.SiO2 supported copper catalyst for gasphase hydrogenation of diethyl oxalate (DEO) was prepared using the ammoniaevaporation method.The catalyst was characterized by the means of X-ray diffraction ( XRD),temperature-programmed reduction (TPR) and highresolution transmission electron microscopy (HRTEM).It was found that copper particles were highly dispersed on the surface of fresh catalyst in small size,and the aggregation of them was the main reason for deactivation.In addition,the results indicated that Cu0 is the main active site for the hydrogenation.