中国材料进展
中國材料進展
중국재료진전
MATERIALS CHINA
2011年
12期
61-64
,共4页
黎明%刘雅超%郭慧尔%闫志巾%吕惠民%阎鹏勋
黎明%劉雅超%郭慧爾%閆誌巾%呂惠民%閻鵬勛
려명%류아초%곽혜이%염지건%려혜민%염붕훈
Zn纳米颗粒%约束弧等离子体电弧法%晶粒形貌
Zn納米顆粒%約束弧等離子體電弧法%晶粒形貌
Zn납미과립%약속호등리자체전호법%정립형모
Zn nano-powders%bound arc discharging plasma method%nano-particle morphology
约束弧等离子体电弧法用等离子体高温热源激发高能粒子的化学反应,并与骤冷技术结合构成一个制备金属纳米粉体或化合物纳米粉末材料的等离子体过程,能极好地制备高溶点(例:Ni,Fe,C等)或低溶点(例:Al,Zn等)的纳米粉末,是当前极具工业化生产应用前景的方法之一。用约束弧等离子体电弧法制备了纳米Zn粉末,用XRD,TEM,TG,DTA技术研究了纳米Zn粉末的结构、晶粒大小、晶粒形貌和热稳定性。结果表明,该粉体平均粒径小于42nm,晶粒形貌为带状,热稳定性好。此外该粉体具有高比表面积,可用作化学反应的催化剂。
約束弧等離子體電弧法用等離子體高溫熱源激髮高能粒子的化學反應,併與驟冷技術結閤構成一箇製備金屬納米粉體或化閤物納米粉末材料的等離子體過程,能極好地製備高溶點(例:Ni,Fe,C等)或低溶點(例:Al,Zn等)的納米粉末,是噹前極具工業化生產應用前景的方法之一。用約束弧等離子體電弧法製備瞭納米Zn粉末,用XRD,TEM,TG,DTA技術研究瞭納米Zn粉末的結構、晶粒大小、晶粒形貌和熱穩定性。結果錶明,該粉體平均粒徑小于42nm,晶粒形貌為帶狀,熱穩定性好。此外該粉體具有高比錶麵積,可用作化學反應的催化劑。
약속호등리자체전호법용등리자체고온열원격발고능입자적화학반응,병여취랭기술결합구성일개제비금속납미분체혹화합물납미분말재료적등리자체과정,능겁호지제비고용점(례:Ni,Fe,C등)혹저용점(례:Al,Zn등)적납미분말,시당전겁구공업화생산응용전경적방법지일。용약속호등리자체전호법제비료납미Zn분말,용XRD,TEM,TG,DTA기술연구료납미Zn분말적결구、정립대소、정립형모화열은정성。결과표명,해분체평균립경소우42nm,정립형모위대상,열은정성호。차외해분체구유고비표면적,가용작화학반응적최화제。
Bound arc discharging plasma method, excited high-energy particles in chemical reactions by high-temperature plasma source, and combined with quenching technology to form a plasma process for preparation of metal or compounds nano-particles, can extremely well prepare the high mehing point (example: Ni, Fe, C, etc. ) or low melting point ( example : Al, Zn, etc. ) nano-powders, is currently a very promising industrial production methods. Nano-powders of Zn were prepared with the bound arc discharging plasma method. The typical structure, particle size, morphology and heat stability of the nano-powders were investigated by XRD, TEM, TG and DTA technologies. The results show that the nano-powders of Zn are nano-sized with the particle size of 42 nm, have band morphology, heat stability. In addition, the nano-powders of Zn can be used as the material in the chemical promoter for its novel character of heat stability and high specific surface area.