陕西师范大学学报:自然科学版
陝西師範大學學報:自然科學版
협서사범대학학보:자연과학판
Journal of Shaanxi Normal University: Nat Sci Ed
2011年
5期
55-61
,共7页
高阳%王海燕%沈淑坤%胡道道
高暘%王海燕%瀋淑坤%鬍道道
고양%왕해연%침숙곤%호도도
P(AM-MAA-VP)%P(AM-MAA-VP)/SiO2复合微球%静电相互作用法
P(AM-MAA-VP)%P(AM-MAA-VP)/SiO2複閤微毬%靜電相互作用法
P(AM-MAA-VP)%P(AM-MAA-VP)/SiO2복합미구%정전상호작용법
P(AM-MAA-VP)%P(AM-MAA-VP)/SiO2 composite microspheres%electrostatic interaction
借助荷正电AEM修饰的P(AM-MAA-VP)微球与荷负电SiO2胶体粒子相互作用,制得具有核壳结构的聚(丙烯酰胺-甲基丙烯酸-乙烯基吡咯烷酮)/SiO2(P(AM-MAA-VP)/SiO2)复合微球材料.结果表明,AEM用量、SiO2胶体溶液的用量、SiO2负载量及后处理方法均会对核壳型复合微球形貌产生一定影响.基于所得到研究结果,可通过改变模板微球及沉积反应前驱体组成,获得具有不同组成的核壳型复合微球材料.
藉助荷正電AEM脩飾的P(AM-MAA-VP)微毬與荷負電SiO2膠體粒子相互作用,製得具有覈殼結構的聚(丙烯酰胺-甲基丙烯痠-乙烯基吡咯烷酮)/SiO2(P(AM-MAA-VP)/SiO2)複閤微毬材料.結果錶明,AEM用量、SiO2膠體溶液的用量、SiO2負載量及後處理方法均會對覈殼型複閤微毬形貌產生一定影響.基于所得到研究結果,可通過改變模闆微毬及沉積反應前驅體組成,穫得具有不同組成的覈殼型複閤微毬材料.
차조하정전AEM수식적P(AM-MAA-VP)미구여하부전SiO2효체입자상호작용,제득구유핵각결구적취(병희선알-갑기병희산-을희기필각완동)/SiO2(P(AM-MAA-VP)/SiO2)복합미구재료.결과표명,AEM용량、SiO2효체용액적용량、SiO2부재량급후처리방법균회대핵각형복합미구형모산생일정영향.기우소득도연구결과,가통과개변모판미구급침적반응전구체조성,획득구유불동조성적핵각형복합미구재료.
The poly(acrylamide-methacrylic acid-N-vinylpyrrolidinone)/silica(P(AM-MAA-VP)/SiO2) composite microspheres with core-shell structure were prepared via electrostatic interaction between negatively charged SiO2 nanoparticles and the positively charged microgels modified by 3-(trimethoxysilyl)-propyldimethyl octadecylammonium chloride(AEM).The results indicated that the surface morphology of composite microspheres with core/shell structure can be affected by the dosage of AEM,the dosage of SiO2 colloid,loading manner and solvent constitute.Based on the results obtained,the method can be used to prepare various composite microspheres with core/shell structure by changing the organic template and inorganic precursor.