负载型固体碱催化合成三氟碘甲烷
부재형고체감최화합성삼불전갑완
Supported solid base-catalyzed synthesis of trifluoroiodo-methane
  • 万方数据
    化学试剂 화학시제
    CHEMICAL REAGENTS
    2010年 3期 273-274 ,共2页

    马洋博%吕剑%张伟%王博

    마양박%려검%장위%왕박

    固体碱%CF_3I%碱金属盐%活性炭 固體堿%CF_3I%堿金屬鹽%活性炭
    고체감%CF_3I%감금속염%활성탄
    solid base%CF_3I%alkali metal salts%activated carbon
    将碱金属、碱土金属盐负载在活性炭载体上制备的多种负载型固体碱作为催化剂,应用于五氟乙烷、氧气和碘合成标题化合物的实验表明,所制备的固体碱中钾盐催化活性高,选择性好,是理想的活性组分.
    장감금속、감토금속염부재재활성탄재체상제비적다충부재형고체감작위최화제,응용우오불을완、양기화전합성표제화합물적실험표명,소제비적고체감중갑염최화활성고,선택성호,시이상적활성조분.
    Supported solid bases were prepared by loading alkali metal salts and alkaline earth metal salts on activated carbon,and were used as catalysts for synthesis of trifluoroiodomethane from C_2F_5H,O_2 and iodine.The results showed that K salt was the optimum catalyst for this reaction.
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