CAJ | 학술논문

研究了负载钛催化剂引发丁二烯在0～40 ℃的本体沉淀聚合动力学。结果表明,体系在单体液相未消失之前转化率与时间成直线关系,即聚合速率恒定,表现为稳态聚合。丁二烯本体沉淀聚合的表观活化能为33.5 kJ／mol。一定条件下的聚合速率方程为:Rp=kp［Bd］0［Ti］0［Al］0。
연구료부재태최화제인발정이희재0～40 ℃적본체침정취합동역학。결과표명,체계재단체액상미소실지전전화솔여시간성직선관계,즉취합속솔항정,표현위은태취합。정이희본체침정취합적표관활화능위33.5 kJ／mol。일정조건하적취합속솔방정위:Rp=kp［Bd］0［Ti］0［Al］0。
The kinetics of bulk precipitation polymerization of butadiene with supported titanium catalysts was studied at 0～40 ℃. The results show that there is a steady polymerization character in this system before the monomer liquid phase disappearing. The apparent active energy calculated was about 33.5 kJ／mol. The kinetic equation of the bulk precipitation polymerization was obtained:Rp=kp［Bd］0［Ti］0［Al］0.