物理化学学报
物理化學學報
물이화학학보
ACTA PHYSICO-CHIMICA SINICA
1999年
6期
560-563
,共4页
苏红梅%吴成印%杨继新%钟晋贤%孔繁敖
囌紅梅%吳成印%楊繼新%鐘晉賢%孔繁敖
소홍매%오성인%양계신%종진현%공번오
CH2%N2O%反应通道%TR-FTIRS
CH2%N2O%反應通道%TR-FTIRS
CH2%N2O%반응통도%TR-FTIRS
CH2%N2O%Reaction dynamics%TR-FTIRS
The reaction dynamics of methylene radicalCH2((x)3B1)with N2O was investigated by Time Resolved Fourier Transform Infrared Spectroscopy(TR-FTIRS). Pure CH2((x)3B1) radical was produced via laser photolysis of ketene at 351 nm.. Nascent vibrationally excited products CO , NO and HCN were observed.. Some reaction pathways which may lead to these products were proposed and a possible reaction mechanism was outlined..