化学学报
化學學報
화학학보
ACTA CHIMICA SINICA
2002年
5期
910-916
,共7页
朱德中%王彤%宋兴民%窦建民%李大成%王大奇%武梅梅%高玉芹
硃德中%王彤%宋興民%竇建民%李大成%王大奇%武梅梅%高玉芹
주덕중%왕동%송흥민%두건민%리대성%왕대기%무매매%고옥근
冠醚%二维网%苯并15-冠一5%二苯并18-冠-6%Pt配合物%合成与结构
冠醚%二維網%苯併15-冠一5%二苯併18-冠-6%Pt配閤物%閤成與結構
관미%이유망%분병15-관일5%이분병18-관-6%Pt배합물%합성여결구
合成了苯并15-冠-5、二苯并18-冠-6与Na2[Pt(SCN)6]的配合物:[Na(B1S-C-5)]2[Pt(SCN)6] (1),[Na(DB18-C-6) ]2[Pt(SCN)6] (2),并通过元素分析、红外光谱、单晶X射线衍射进行了表征.1为单斜晶系,空间群P21/c,a=1.0974(5) nm,b=1.5187(7)nm,c=1.3632(6)nm,β= 96.407(7)°,V=2.2568(18)nm3,Z=2,Dcalcd=1.746g/cm3,F(000)=1184,R1=0.0357,wR2=0.0868.2为三斜晶系,空间群 P1,a=1.2500(3)nm,b=1.2825(3)nm,c = 1.9342(4) nm,α = 106.82(3)°,β= 102.51(3)°,γ= 103.04(3)°,V= 2.7562 nm3,Z = 2,Dcalcd = 1.579 g/cm3,F(000) = 1316,R1 =0.0364,wR2 = 0.0771.配合物分别由两个[Na(B15-C-5)]+,[Na(DB18-C-6)] + 配阳离子和一个[Pt(SCN)6]2-配阴离子组成.配阳离子和配阴离子通过Na-N键形成二维网状结构.
閤成瞭苯併15-冠-5、二苯併18-冠-6與Na2[Pt(SCN)6]的配閤物:[Na(B1S-C-5)]2[Pt(SCN)6] (1),[Na(DB18-C-6) ]2[Pt(SCN)6] (2),併通過元素分析、紅外光譜、單晶X射線衍射進行瞭錶徵.1為單斜晶繫,空間群P21/c,a=1.0974(5) nm,b=1.5187(7)nm,c=1.3632(6)nm,β= 96.407(7)°,V=2.2568(18)nm3,Z=2,Dcalcd=1.746g/cm3,F(000)=1184,R1=0.0357,wR2=0.0868.2為三斜晶繫,空間群 P1,a=1.2500(3)nm,b=1.2825(3)nm,c = 1.9342(4) nm,α = 106.82(3)°,β= 102.51(3)°,γ= 103.04(3)°,V= 2.7562 nm3,Z = 2,Dcalcd = 1.579 g/cm3,F(000) = 1316,R1 =0.0364,wR2 = 0.0771.配閤物分彆由兩箇[Na(B15-C-5)]+,[Na(DB18-C-6)] + 配暘離子和一箇[Pt(SCN)6]2-配陰離子組成.配暘離子和配陰離子通過Na-N鍵形成二維網狀結構.
합성료분병15-관-5、이분병18-관-6여Na2[Pt(SCN)6]적배합물:[Na(B1S-C-5)]2[Pt(SCN)6] (1),[Na(DB18-C-6) ]2[Pt(SCN)6] (2),병통과원소분석、홍외광보、단정X사선연사진행료표정.1위단사정계,공간군P21/c,a=1.0974(5) nm,b=1.5187(7)nm,c=1.3632(6)nm,β= 96.407(7)°,V=2.2568(18)nm3,Z=2,Dcalcd=1.746g/cm3,F(000)=1184,R1=0.0357,wR2=0.0868.2위삼사정계,공간군 P1,a=1.2500(3)nm,b=1.2825(3)nm,c = 1.9342(4) nm,α = 106.82(3)°,β= 102.51(3)°,γ= 103.04(3)°,V= 2.7562 nm3,Z = 2,Dcalcd = 1.579 g/cm3,F(000) = 1316,R1 =0.0364,wR2 = 0.0771.배합물분별유량개[Na(B15-C-5)]+,[Na(DB18-C-6)] + 배양리자화일개[Pt(SCN)6]2-배음리자조성.배양리자화배음리자통과Na-N건형성이유망상결구.
