化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2010年
3期
691-698
,共8页
辛寅昌%马磊%卞介萍%董晓燕%赵明方%侯尔群
辛寅昌%馬磊%卞介萍%董曉燕%趙明方%侯爾群
신인창%마뢰%변개평%동효연%조명방%후이군
耐盐表面活性剂%高矿化度洗涤%高矿化度稠油开采
耐鹽錶麵活性劑%高礦化度洗滌%高礦化度稠油開採
내염표면활성제%고광화도세조%고광화도주유개채
salt-resisting surfactant%high-salinity water washing%high salinity heavy oil
由于高矿化度水含盐量大、表面张力高、腐蚀性强,一般表面活性剂在高矿化度的水中的活性极大降低,所以在海水中不能用一般表面活性剂作为洗涤剂使用.文献报道某些特殊功能的表面活性剂耐受矿化度范围是110000 mg·L~(-1)以下(碱土金属只能在2500 mg·L~(-1)以内).复合α-烯基高分子聚醚羧酸盐耐受碱金属盐高达150000 mg·L~(-1),其中,耐受碱土金属高达20000 mg·L~(-1)左右.用于海水洗涤具有优异的洗涤效果和防锈、防腐蚀效果;用在高矿化度稠油开采中,能把储层矿化度高达150000 mg·L~(-1)左右、碱土金属高达20000 mg·L~(-1)左右的黏度高达100000 mPa·s (50℃)以上的特稠油乳化降黏至50 mPa·s (50℃)以下.
由于高礦化度水含鹽量大、錶麵張力高、腐蝕性彊,一般錶麵活性劑在高礦化度的水中的活性極大降低,所以在海水中不能用一般錶麵活性劑作為洗滌劑使用.文獻報道某些特殊功能的錶麵活性劑耐受礦化度範圍是110000 mg·L~(-1)以下(堿土金屬隻能在2500 mg·L~(-1)以內).複閤α-烯基高分子聚醚羧痠鹽耐受堿金屬鹽高達150000 mg·L~(-1),其中,耐受堿土金屬高達20000 mg·L~(-1)左右.用于海水洗滌具有優異的洗滌效果和防鏽、防腐蝕效果;用在高礦化度稠油開採中,能把儲層礦化度高達150000 mg·L~(-1)左右、堿土金屬高達20000 mg·L~(-1)左右的黏度高達100000 mPa·s (50℃)以上的特稠油乳化降黏至50 mPa·s (50℃)以下.
유우고광화도수함염량대、표면장력고、부식성강,일반표면활성제재고광화도적수중적활성겁대강저,소이재해수중불능용일반표면활성제작위세조제사용.문헌보도모사특수공능적표면활성제내수광화도범위시110000 mg·L~(-1)이하(감토금속지능재2500 mg·L~(-1)이내).복합α-희기고분자취미최산염내수감금속염고체150000 mg·L~(-1),기중,내수감토금속고체20000 mg·L~(-1)좌우.용우해수세조구유우이적세조효과화방수、방부식효과;용재고광화도주유개채중,능파저층광화도고체150000 mg·L~(-1)좌우、감토금속고체20000 mg·L~(-1)좌우적점도고체100000 mPa·s (50℃)이상적특주유유화강점지50 mPa·s (50℃)이하.
As its activity falls in high salinity water, the usual surfactant cannot be used for washing because of much salt, and increased surface tension and corrosion.It was reported in literature that some special surfactant can resist salinity up to 110000 mg·L~(-1) (alkaline earth metals up to 2500 mg·L~(-1)).A compound α-olefine polyether carboxylate whose range of resisting salinity up to 150000 mg·L~(-1) (alkaline earth metals up to 20000 mg·L~(-1))was introduced.Its washing and anti-corrosion effect in sea water was excellent.In the production of high-salinity heavy oil, it can reduce the viscosity of oil with formation water salinity as high as 150000 mg·L~(-1) (alkaline earth metals up to 20000 mg·L~(-1))from 100000 mPa·s (50℃) to 50 mPa·s (50℃).