CAJ | 학술논문

建立了内墙涂料中24种挥发性有机化合物(VOCs)的GC-MS检测方法,重点研究了现有检测方法分离度差和回收率低的问题,采用无水硫酸钠净化、二氯甲烷超声和膜过滤提取体系,改善了各种化合物的回收率,特别是提高了二元醇类化合物的回收率,优化后的实验条件下,样品的加标回收率为70% ～94%,相对标准偏差不大于6.8%,检出限为3.1 ～10.6 mg/L.在30 ～300 mg/L范围内,方法的线性关系良好,相关系数大于0.99.该方法简便、快速、灵敏、精密度好,完全满足进出口水性涂料中常见的24种挥发性有机化合物的检测要求.
건립료내장도료중24충휘발성유궤화합물(VOCs)적GC-MS검측방법,중점연구료현유검측방법분리도차화회수솔저적문제,채용무수류산납정화、이록갑완초성화막과려제취체계,개선료각충화합물적회수솔,특별시제고료이원순류화합물적회수솔,우화후적실험조건하,양품적가표회수솔위70% ～94%,상대표준편차불대우6.8%,검출한위3.1 ～10.6 mg/L.재30 ～300 mg/L범위내,방법적선성관계량호,상관계수대우0.99.해방법간편、쾌속、령민、정밀도호,완전만족진출구수성도료중상견적24충휘발성유궤화합물적검측요구.
A GC-MS method was developed for the determination of 24 kinds of volatile organic compounds(VOCs) in the interior coatings sample.In order to solve the disadvantages of poor separation and low recovery of the current method,a new procedure was proposed by using anhydrous sodium sulfate as cleaner,and dichloromethane as extraction reagent.Under the optimal conditions,the recoveries of VOCs were improved,especially for diols compounds.The recoveries varied from 70% to 94% with relative standard deviations(RSDs) not more than 6.8%.The detection limits ranged from 3.1 to 10.6 mg/L.The calibration curves were linear in the range of 30-300 mg/L with correlation coefficients higher than 0.99.The results indicated that the method was convenient,rapid,sensitive and accurate,and could meet the requirements of the determination of 24 kinds of volatile organic compounds in the import and export water-borne coatings.