无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2011年
7期
1405-1410
,共6页
王世铭%袁洋%王琼生%颜桂炀
王世銘%袁洋%王瓊生%顏桂煬
왕세명%원양%왕경생%안계양
铜配合物%晶体结构%L-苹果酸%超分子%钼
銅配閤物%晶體結構%L-蘋果痠%超分子%鉬
동배합물%정체결구%L-평과산%초분자%목
copper complex%crystal structure%L-malic acid%supramolecular%,molybdenum
本文用铜、邻菲咯啉、钼酸铵和苹果酸合成了1种新型配合物Cu2(phen)2(μ-O)2Mo(C4H3O5)2· 7H2O(1,phen=1,10-邻菲咯啉,C4H3O53-=苹果酸根阴离子),并对它进行了单晶X射线衍射,红外光谱,元素分析等表征.X射线衍射分析表明配合物为苹果酸和邻菲咯啉桥联形成的三核铜及钼中心的一维螺旋链状结构,并通过氢键自组装成三维超分子化合物.另外,对配合物的固态的固体荧光性能也进行了研究.
本文用銅、鄰菲咯啉、鉬痠銨和蘋果痠閤成瞭1種新型配閤物Cu2(phen)2(μ-O)2Mo(C4H3O5)2· 7H2O(1,phen=1,10-鄰菲咯啉,C4H3O53-=蘋果痠根陰離子),併對它進行瞭單晶X射線衍射,紅外光譜,元素分析等錶徵.X射線衍射分析錶明配閤物為蘋果痠和鄰菲咯啉橋聯形成的三覈銅及鉬中心的一維螺鏇鏈狀結構,併通過氫鍵自組裝成三維超分子化閤物.另外,對配閤物的固態的固體熒光性能也進行瞭研究.
본문용동、린비각람、목산안화평과산합성료1충신형배합물Cu2(phen)2(μ-O)2Mo(C4H3O5)2· 7H2O(1,phen=1,10-린비각람,C4H3O53-=평과산근음리자),병대타진행료단정X사선연사,홍외광보,원소분석등표정.X사선연사분석표명배합물위평과산화린비각람교련형성적삼핵동급목중심적일유라선련상결구,병통과경건자조장성삼유초분자화합물.령외,대배합물적고태적고체형광성능야진행료연구.
A novel complex Cu2(phen)2(μ-O)2Mo(C4H3O5)2·7H2O (1,phen=1,10-phenanthroline,C4H3O3-5-=malate dianion) has been prepared by reaction of copper,phen,ammonium molybdate and L-malic acid in solution and characterized by single-crystal X-ray diffraction analysis,FTIR spectroscopy and elemental analysis.X-ray diffraction reveals that complex 1 consists of molybdenum centers bridged by malate and Cu-phen ligands,which are linked into 1D spiral-shaped chains and self-assembled to form 3D supramolecular architectures via hydrogen bonds.In addition,the photoluminescent properties in solid state were investigated.CCDC:809924.
