D,L-1,2,2-三甲基环戊烷-1,3-二胺硝酸镍配合物的合成、结构及其和手性D-(+)-1,2,2-三甲基环戊烷-1,3-二胺氯化镍配合物的对比分析
D,L-1,2,2-삼갑기배무완-1,3-이알초산얼배합물적합성、결구급기화수성D-(+)-1,2,2-삼갑기배무완-1,3-이알록화얼배합물적대비분석
Synthesis and Crystal Structure of a Nickel(Ⅱ) Complex [Ni(La)2](NO3)2 (La=D,L-1,2,2-trimethylcyclopentane-1,3-diamine) and Its Comparison with Chiral Complex [Ni(Lb)2]Cl2·2H2O (Lb=D-(+)-1,2,2-trimethylcyclopentane-1,3-diamine)
  • 万方数据
    无机化学学报 무궤화학학보
    JOURNAL OF INORGANIC CHEMISTRY
    2004年 2期 205-209 ,共5页

    黄伟%周云曙%李卉卉%钱惠芬%苟少华

    황위%주운서%리훼훼%전혜분%구소화

    D,L-1,2,2-三甲基环戊烷-1,3-二胺 镍配合物 晶体结构 氢键相互作用 D,L-1,2,2-三甲基環戊烷-1,3-二胺 鎳配閤物 晶體結構 氫鍵相互作用
    D,L-1,2,2-삼갑기배무완-1,3-이알 얼배합물 정체결구 경건상호작용
    D,L-1,2,2-trimethylcyclopentane-1,3-diamine%nickel(Ⅱ) complex%crystal structure%hydrogen bonding interactions


    A nickel(Ⅱ)complex [Ni(La)2](NO3)2(1)with bidentate racemic 1,2,2-trimethylcylopentane-1,3-diamine ligand has been synthesized and characterized by IR,EA,ES-MS,and its X-ray diffraction study reveals that the nickel(Ⅱ) center is tetra-coordinated by one D-and one L-diamine ligands,and t three-dimensional Hydrogen-bond-sustained network is formed in the solid state by means of the eight-membered N-H…O hydrogen bond cycle.This compound also supplies a good comparison to the chiral complex[Ni(Lb)2]Cl2·2H2O(2)(Lb=D-(+)-1,2,2-trimethylcyclopentane-1,3-diamine).CCDC:218122
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