石油炼制与化工
石油煉製與化工
석유련제여화공
PETROLEUM PROCESSING AND PETROCHEMICALS
2009年
9期
1-7
,共7页
马爱增%张大庆%潘锦程%任坚强
馬愛增%張大慶%潘錦程%任堅彊
마애증%장대경%반금정%임견강
汽油%苯%催化重整异构化%改质
汽油%苯%催化重整異構化%改質
기유%분%최화중정이구화%개질
gasoline%benzene%catalytic reforming%isomerization%upgrading
针对降低车用汽油中苯含量的问题,分析了苯的来源,指出催化重整装置重整生成油中的苯是汽油中苯的主要来源.对降低重整生成油中苯含量的技术途径进行了探讨,指出选择适合的重整操作方案、预分馏脱除重整原料中的苯以及苯的前驱体、从重整生成油中脱除苯是降低苯的主要途径.对预分馏馏分以及重整生成油中苯的后加工技术进行探讨,并对5种降低苯含量的技术进行对比.不同的技术方案对产物的收率影响较大,企业可以根据各自的具体情况进行选择.
針對降低車用汽油中苯含量的問題,分析瞭苯的來源,指齣催化重整裝置重整生成油中的苯是汽油中苯的主要來源.對降低重整生成油中苯含量的技術途徑進行瞭探討,指齣選擇適閤的重整操作方案、預分餾脫除重整原料中的苯以及苯的前驅體、從重整生成油中脫除苯是降低苯的主要途徑.對預分餾餾分以及重整生成油中苯的後加工技術進行探討,併對5種降低苯含量的技術進行對比.不同的技術方案對產物的收率影響較大,企業可以根據各自的具體情況進行選擇.
침대강저차용기유중분함량적문제,분석료분적래원,지출최화중정장치중정생성유중적분시기유중분적주요래원.대강저중정생성유중분함량적기술도경진행료탐토,지출선택괄합적중정조작방안、예분류탈제중정원료중적분이급분적전구체、종중정생성유중탈제분시강저분적주요도경.대예분류류분이급중정생성유중분적후가공기술진행탐토,병대5충강저분함량적기술진행대비.불동적기술방안대산물적수솔영향교대,기업가이근거각자적구체정황진행선택.
Based on analyzing the benzene content of blending components in gasoline pool,it is concluded that reformate is the key benzene source of gasoline.Technologic approaches for reducing benzene content of reformate are reviewed.It is proposed that selecting the optimum catalytic reformer modes and operation conditions,adopting pre-fractionation to remove benzene and benzene precursors from feed and removing benzene from reformate are the three main approaches to reduce benzene content.Discussions of pre-fractionation and post processing of reformate are conducted in detail including the utilization of light naphtha,isomerazation,benzene saturation,benzene extraction and benzene alkylation. Finally,five processing schemes for reducing the benzene content of reformate from conventional naphtha feed are compared and put forward for refineries to select according to their own requirements.