化学物理学报
化學物理學報
화학물이학보
CHINESE JOURNAL OF CHEMICAL PHYSICS
2006年
3期
259-264
,共6页
孔纪兰%周上祺%任勤%张喜
孔紀蘭%週上祺%任勤%張喜
공기란%주상기%임근%장희
纳米碳管%Ni-P%化学复合镀%组织%结构
納米碳管%Ni-P%化學複閤鍍%組織%結構
납미탄관%Ni-P%화학복합도%조직%결구
Carbon nanotubes%Ni-P%Electroless composite plating%Constitution%Structure
采用化学复合镀方法,在基体铜片上进行Ni-P/纳米碳管复合镀.用金相显微镜、扫描电子显微镜、X射线衍射仪和显微硬度计等实验手段研究复合镀层的组织、结构和性能.结果表明:随着镀液中纳米碳管含量的增加,复合镀层表面的颗粒变小且密度增加;复合镀层的硬度随纳米碳管含量的增加而提高;此外,纳米碳管的加入,使镀层由非晶变成了纳米晶,促进了复合镀层的晶化.
採用化學複閤鍍方法,在基體銅片上進行Ni-P/納米碳管複閤鍍.用金相顯微鏡、掃描電子顯微鏡、X射線衍射儀和顯微硬度計等實驗手段研究複閤鍍層的組織、結構和性能.結果錶明:隨著鍍液中納米碳管含量的增加,複閤鍍層錶麵的顆粒變小且密度增加;複閤鍍層的硬度隨納米碳管含量的增加而提高;此外,納米碳管的加入,使鍍層由非晶變成瞭納米晶,促進瞭複閤鍍層的晶化.
채용화학복합도방법,재기체동편상진행Ni-P/납미탄관복합도.용금상현미경、소묘전자현미경、X사선연사의화현미경도계등실험수단연구복합도층적조직、결구화성능.결과표명:수착도액중납미탄관함량적증가,복합도층표면적과립변소차밀도증가;복합도층적경도수납미탄관함량적증가이제고;차외,납미탄관적가입,사도층유비정변성료납미정,촉진료복합도층적정화.
The electroless Ni-P-carbon nanotubes composite plating was studied on the copper substrate. Metallurgical microscope, scanning electronic microscope, X-ray diffractometer and micro hardness tester were used to study the structure, constitution and performance of the electroless Ni-P-carbon nanotubes composite deposit. Experiential results show that, with the increment of carbon nanotubes content in electroless plating solution, the grain size on the sample surface decreases whereas the density of grains and the hardness for composite deposit increases. Moreover, adding carbon nanotubes not only improves the degree of crystallization for the composite deposit but also helps their transformation from the amorphous state to the nanocrystal state.