环境工程学报
環境工程學報
배경공정학보
CHINESE JOURNAL OF ENVIRONMENTAL ENGINEERING
2010年
4期
904-908
,共5页
黄明%许立巍%何强%林华%乔凤美
黃明%許立巍%何彊%林華%喬鳳美
황명%허립외%하강%림화%교봉미
污泥%元素硫%氧化硫硫杆菌%生物沥滤
汙泥%元素硫%氧化硫硫桿菌%生物瀝濾
오니%원소류%양화류류간균%생물력려
surplus sludge%elemental sulfur%Acidithiobacillus thiooxidans%bioleaching
以城市污水处理厂剩余污泥作为处理介质,土著嗜酸氧化硫硫杆菌(Acidithiobacillus thiooxidans,A.thiooxi-dans)为主要沥滤微生物,采用序批式生物沥滤装置,就投加150~725 μm的不同粒径元素硫对沥滤的酸化效果、硫酸根产率和重金属去除效果的影响进行了研究.结果表明,在元素硫投配量为3 g/L,曝气强度为1.0L/(min·L)的条件下,元素硫粒径在165~215 μm范围减小时能显著改善污泥酸化速度、提高酸化程度和硫酸根产率.底物元素硫的最佳粒径为165μm,此时沥滤体系pH下降速率为0.85个pH单位/d,硫酸根的产率为454.9 mg/(L·d),沥滤6d后污泥中高浓度重金属Cu、Zn、Cd的去除率达到70. 3%、81. 2%、87.8%.
以城市汙水處理廠剩餘汙泥作為處理介質,土著嗜痠氧化硫硫桿菌(Acidithiobacillus thiooxidans,A.thiooxi-dans)為主要瀝濾微生物,採用序批式生物瀝濾裝置,就投加150~725 μm的不同粒徑元素硫對瀝濾的痠化效果、硫痠根產率和重金屬去除效果的影響進行瞭研究.結果錶明,在元素硫投配量為3 g/L,曝氣彊度為1.0L/(min·L)的條件下,元素硫粒徑在165~215 μm範圍減小時能顯著改善汙泥痠化速度、提高痠化程度和硫痠根產率.底物元素硫的最佳粒徑為165μm,此時瀝濾體繫pH下降速率為0.85箇pH單位/d,硫痠根的產率為454.9 mg/(L·d),瀝濾6d後汙泥中高濃度重金屬Cu、Zn、Cd的去除率達到70. 3%、81. 2%、87.8%.
이성시오수처리엄잉여오니작위처리개질,토저기산양화류류간균(Acidithiobacillus thiooxidans,A.thiooxi-dans)위주요력려미생물,채용서비식생물력려장치,취투가150~725 μm적불동립경원소류대력려적산화효과、류산근산솔화중금속거제효과적영향진행료연구.결과표명,재원소류투배량위3 g/L,폭기강도위1.0L/(min·L)적조건하,원소류립경재165~215 μm범위감소시능현저개선오니산화속도、제고산화정도화류산근산솔.저물원소류적최가립경위165μm,차시력려체계pH하강속솔위0.85개pH단위/d,류산근적산솔위454.9 mg/(L·d),력려6d후오니중고농도중금속Cu、Zn、Cd적거제솔체도70. 3%、81. 2%、87.8%.
In this research, surplus sludge taken from a wastewater treatment plant(WWTP) was used as
the bioleaching medium, and indigenous AcidithiobaciUus thiooxidans was the main bioleaching microorganism in bioleaching process. The acidification effect of sewage sludge, activity of bioleaching microorganism and removal rate of heavy metals were investigated with various elemental sulfur particle sizes from 150μm to 725μm. This experiment was conducted in sequence batch bioleaching reactor with 3 g/L of S~0 dosage and aeration rate of 1.0 L/(min · L). The results showed that sludge acidification speed, sludge acidification level and sulfate production rate could be improved significantly when sulfur particle size decreased from 215μm to 165μm. And 165 μm was determined as the optimum elemental sulfur particle size for bioleaching process. Under this condition, pH decreasing rate and sulfate ions yield rate was 0.85 pH/d and 454.9 mg/(L · d) respectively, the removal rates of Cu, Zn and Cd were 70.3% 、81.2% and 87.8%, respectively after 6 days' bioleaching.