CAJ | 학술논문

研究了18-冠-6分别与Na2[M(mnt)2][M=Cu,Ni;mnt=丁二腈烯二硫醇阴离子,C2S2(CN)22-]的反应,得到的配合物{[Na(18-C-6)][Na(18-C-6)(H2O)]}[Cu(mnt)2](1),[Na(18-C-6)(H2O)]2[Ni(mnt)2]@(18-C-6)(2)通过元素分析、红外光谱、X射线单晶衍射进行了表征.两个配合物均为三斜晶系,空间群P1.1的晶体学结构数据:a=1.22697(19)nm,b=1.22780(19)nm,c=1.5665(3)nm,α=95.083(3)°,β=101.534(3)°,y=91.007(3)°,V=2.3016(6)nm3,Z=2,Dcalcd=1.350g/cm3,F(000)=976,R1=0.0726,wR2=0.1843.2的晶体学结构数据:a=1.11620(17)nm,b=1.22054(18)nm,c=1.27939(18)nm,α=111.647(2)°,β=92.792(3)°,y=103.201(2)°,V=2.5461(4)nm3,Z=1,Dcalcd=1.304g/~cm3,F(000)=642,R1=0.0459,wR2=0.1003.1中的[Cu(mnt)2]2-通过mnt的氮原子与[Na(18-C-6)]+中的钠原子成键,形成了一维链状结构;[Na(18-C-6)(H2O)]+只起平衡电荷的作用.2中的[Ni(mnt)2]2-也通过配体的mnt氮原子与两个[Na(18-C-6)(H2O)]+中的钠原子成键,形成稳定的中性配合物.
연구료18-관-6분별여Na2[M(mnt)2][M=Cu,Ni;mnt=정이정희이류순음리자,C2S2(CN)22-]적반응,득도적배합물{[Na(18-C-6)][Na(18-C-6)(H2O)]}[Cu(mnt)2](1),[Na(18-C-6)(H2O)]2[Ni(mnt)2]@(18-C-6)(2)통과원소분석、홍외광보、X사선단정연사진행료표정.량개배합물균위삼사정계,공간군P1.1적정체학결구수거:a=1.22697(19)nm,b=1.22780(19)nm,c=1.5665(3)nm,α=95.083(3)°,β=101.534(3)°,y=91.007(3)°,V=2.3016(6)nm3,Z=2,Dcalcd=1.350g/cm3,F(000)=976,R1=0.0726,wR2=0.1843.2적정체학결구수거:a=1.11620(17)nm,b=1.22054(18)nm,c=1.27939(18)nm,α=111.647(2)°,β=92.792(3)°,y=103.201(2)°,V=2.5461(4)nm3,Z=1,Dcalcd=1.304g/~cm3,F(000)=642,R1=0.0459,wR2=0.1003.1중적[Cu(mnt)2]2-통과mnt적담원자여[Na(18-C-6)]+중적납원자성건,형성료일유련상결구;[Na(18-C-6)(H2O)]+지기평형전하적작용.2중적[Ni(mnt)2]2-야통과배체적mnt담원자여량개[Na(18-C-6)(H2O)]+중적납원자성건,형성은정적중성배합물.