CAJ | 학술논문

合成了1个以粘液酸为配体的锰(Ⅱ)配合物Mn[(muc)(H2O)3]·H2O(1),并通过红外光谱,元素分析,热重分析和X-射线单晶衍射对其进行了表征.配合物1由一维链组成,其三维网络结构可以简化为dia拓扑.初步的电化学实验表明,配合物1在电化学储能上有应用潜力,可以作为氢氧化镍电极的添加剂.
합성료1개이점액산위배체적맹(Ⅱ)배합물Mn[(muc)(H2O)3]·H2O(1),병통과홍외광보,원소분석,열중분석화X-사선단정연사대기진행료표정.배합물1유일유련조성,기삼유망락결구가이간화위dia탁복.초보적전화학실험표명,배합물1재전화학저능상유응용잠력,가이작위경양화얼전겁적첨가제.
A new manganese complex [Mn(muc)(H2O)3]·H2O (1) (H2muc=mucic acid) has been synthesized and characterized by X-ray single-crystal diffraction, elemental analysis, IR spectrum, and thermogravimetry analysis.The structure of 1 is composed of 1D chains and further joined by hydrogen bonds to construct a 3D supramolecule structure. Preliminary electrochemical experiments indicated that as an additive on nickel hydroxide electrodes 1 could improve the electrochemical performance and has potential applications in electrochemical storage.