中国炼油与石油化工(英文版)
中國煉油與石油化工(英文版)
중국련유여석유화공(영문판)
CHINA PETROLEUM PROCESSING AND PETROCHEMICAL TECHNOLOGY
2005年
1期
57-61
,共5页
Transition metal%catalyst%polyethylene%low molecular weight
Nickel-based catalyst [N,N]NiBr2, in which [N,N] stands for N-(2,6-diisopropylphenyl)pyridine-2-carboxaldimine, shows high activity for ethylene polymerization in the presence of organoaluminum compounds under high ethylene pressure to yield polyethylene characteristic of low molecular weight and highly branched chains. Toluene as the solvent is more in favor of catalyst activity, higher molecular weight and branched chains in polyethylene structure as compared to hexane solvent.