电化学
電化學
전화학
2001年
1期
109-119
,共11页
林化新%衣宝廉%周利%何长青%孔连英%张恩浚
林化新%衣寶廉%週利%何長青%孔連英%張恩浚
림화신%의보렴%주리%하장청%공련영%장은준
电池隔膜%补偿隔膜收缩%带铸法%MCFC性能
電池隔膜%補償隔膜收縮%帶鑄法%MCFC性能
전지격막%보상격막수축%대주법%MCFC성능
用γ-LiAO2粉料和带铸法制备电池隔膜。隔膜有很高的阻窜能力和较低的欧姆极化。在电流密度为200和246 mA/cm2下放电时,用此膜组装的电池组(三对电池,电极面积为122 cm2)输出电压分别为2.01和1.78 V,输出功率达53.4 W.于200和300 mA/cm2下放电时,单电池(电极面积为28 cm2)输出电压分别高于0.85和0.75 V, 输出功率约6.6 W. 补偿隔膜收缩导致电池性能的提高.
用γ-LiAO2粉料和帶鑄法製備電池隔膜。隔膜有很高的阻竄能力和較低的歐姆極化。在電流密度為200和246 mA/cm2下放電時,用此膜組裝的電池組(三對電池,電極麵積為122 cm2)輸齣電壓分彆為2.01和1.78 V,輸齣功率達53.4 W.于200和300 mA/cm2下放電時,單電池(電極麵積為28 cm2)輸齣電壓分彆高于0.85和0.75 V, 輸齣功率約6.6 W. 補償隔膜收縮導緻電池性能的提高.
용γ-LiAO2분료화대주법제비전지격막。격막유흔고적조찬능력화교저적구모겁화。재전류밀도위200화246 mA/cm2하방전시,용차막조장적전지조(삼대전지,전겁면적위122 cm2)수출전압분별위2.01화1.78 V,수출공솔체53.4 W.우200화300 mA/cm2하방전시,단전지(전겁면적위28 cm2)수출전압분별고우0.85화0.75 V, 수출공솔약6.6 W. 보상격막수축도치전지성능적제고.
The matrix prepared with γ-LiAlO2 powder and by tape cast displayed higher ability of preventing from gas cross-over and lower ohmic polarization. The voltages of the stack (three cells,122 cm2) stacked with the matrix were 2.02 and 1.78 V at 200 and 246 mA/cm2, respectively, and the output power reached 53.4 W. The cell(28 cm2) voltages were 0.85 and 0.75 V at 200 and 300 mA/cm2, respectively,and the output power was about 6.6 W. Compensating the shrinkage of matrix in stacking cells promoted the enhancement of the MCFC performance.