物理化学学报
物理化學學報
물이화학학보
ACTA PHYSICO-CHIMICA SINICA
1999年
7期
643-646
,共4页
杨继新%苏红梅%毛文涛%钟晋贤%孔繁敖
楊繼新%囌紅梅%毛文濤%鐘晉賢%孔繁敖
양계신%소홍매%모문도%종진현%공번오
CH2(~X3B1)%态-态反应%TR-FTIR%NO
CH2(~X3B1)%態-態反應%TR-FTIR%NO
CH2(~X3B1)%태-태반응%TR-FTIR%NO
CH2(~X3B1)%State-specific reaction%TR-FTIR%NO
The reaction of methylene radicals in their 3B1 electronic ground state with molecular NO was studied. Pure CH2(~X3B1) radicals were produced by UV photolysis of ketene at 351 nm. The products were measured by Time-Resolved Fourier Transform Infrared (TR-FTIR) spectrometer. CO、OH、NH2 and HOCN or its isomer HNCO were found as primary products and several possible channels of this reaction were suggested.