无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2008年
5期
823-826
,共4页
Schiff base%nicke(Ⅱ)complex%crystal structure%electrochemcal%measurements%thermal analysis
The complex,[Ni(C13H7Br2NOS)2(DMF)]·(C3H7O) (DMF=N,N'-dimethylformamide), was synthesized and characterized by the element analysis, IR and X-ray diffraction single crystal structure determination. The title complex crystallizes in monoclinic system, space group P21/n, with a=8.297 6(15) nm, b=12.866(2) nm, c=31.889(3)nm, β=95.024(2)°, and V=3 391.3(9) nm3, Z-4, R=0.075 2, wR=0.176 8. The nickel iron is six-coordinated by three O atoms, two N atoms, one S from the Schiff base and one O atom from DMF ligand, forming a octahedron coordination geometry. Schiff bases are bridged by the two S atoms. The molecules in the crystal are linked through intermolecular Br…Br, C-H…O, S… Br interactions. Its electrochemical property is reported. CCDC: 675768.
