石油学报(石油加工)
石油學報(石油加工)
석유학보(석유가공)
ACTA PETROLEI SINICA(PETROLEUM PROCESSING SECTION)
2010年
2期
219-224
,共6页
李传%张龙力%王继乾%邓文安%阙国和
李傳%張龍力%王繼乾%鄧文安%闕國和
리전%장룡력%왕계건%산문안%궐국화
渣油%流变特性%饱和分%沥青质
渣油%流變特性%飽和分%瀝青質
사유%류변특성%포화분%력청질
residue%rheological properties%saturates%asphaltene
采用Rheostress300型流变仪和偏光显微镜测定了大庆常压渣油(DQAR)的流型、流型转变特点、黏-温关系和蜡晶形貌等流变性特征,并分析了渣油饱和分和沥青质对DQAR流变特性的影响.结果表明,DQAR在低温下均为假塑性流体,在高温下转型为牛顿流体,其流型转变温度为50℃.饱和分的加入能使大庆常压渣油蜡晶晶粒变大,网状结构更加紧凑,流型转变温度升高,并使渣油在非牛顿流型区域的黏度急剧增加;而沥青质在整个温度范围内,均能使渣油黏度增大,基本不影响DQAR蜡晶形貌.
採用Rheostress300型流變儀和偏光顯微鏡測定瞭大慶常壓渣油(DQAR)的流型、流型轉變特點、黏-溫關繫和蠟晶形貌等流變性特徵,併分析瞭渣油飽和分和瀝青質對DQAR流變特性的影響.結果錶明,DQAR在低溫下均為假塑性流體,在高溫下轉型為牛頓流體,其流型轉變溫度為50℃.飽和分的加入能使大慶常壓渣油蠟晶晶粒變大,網狀結構更加緊湊,流型轉變溫度升高,併使渣油在非牛頓流型區域的黏度急劇增加;而瀝青質在整箇溫度範圍內,均能使渣油黏度增大,基本不影響DQAR蠟晶形貌.
채용Rheostress300형류변의화편광현미경측정료대경상압사유(DQAR)적류형、류형전변특점、점-온관계화사정형모등류변성특정,병분석료사유포화분화력청질대DQAR류변특성적영향.결과표명,DQAR재저온하균위가소성류체,재고온하전형위우돈류체,기류형전변온도위50℃.포화분적가입능사대경상압사유사정정립변대,망상결구경가긴주,류형전변온도승고,병사사유재비우돈류형구역적점도급극증가;이력청질재정개온도범위내,균능사사유점도증대,기본불영향DQAR사정형모.
The rheological properties of Daqing atmospheric residue(DQAR), such as flow pattern, flow pattern change temperature, viscosity-temperature curve, wax shape and so on, were investigated by using Rheostress300 rheometer and polarized light microscopy, and the effects of saturates and asphaltene on the rheological properties of DQAR were analyzed. It is found that DQAR was a Pseudoplastic fluid at low temperature and a Newton fluid at high temperature, and the flow pattern change temperature of DQAR was 50℃. The addition of saturates in DQAR can make the wax particle bigger and grid structure more compact, the flow pattern change temperature increase, and make the viscosity of residue increase quickly in the field of non-Newton fluid, while the addition of asphaltene can increase the viscosity of DQAR all the way without affecting the wax shape basically.