生物质化学工程
生物質化學工程
생물질화학공정
BIOMASS CHEMICAL ENGINEERING
2011年
5期
17-20
,共4页
庄晓伟%穆有炳%潘炘%章江丽%王春鹏%赵临五
莊曉偉%穆有炳%潘炘%章江麗%王春鵬%趙臨五
장효위%목유병%반흔%장강려%왕춘붕%조림오
碱木质素%羟甲基化%酚醛胶%竹胶板
堿木質素%羥甲基化%酚醛膠%竹膠闆
감목질소%간갑기화%분철효%죽효판
alkali lignin%hydroxymethylated%phenol-formaldehyde adhesive%bamboo plywood
采用羟甲基化碱木质素(HKLF)与酚醛树脂(PF)复合制备碱木质素-酚醛复合胶黏剂(KPF),研究了HKLF添加量对KPF性能的影响,并分析其在竹胶板中应用的可行性。结果表明:HKLF添加量为10%~30%的KPF生产的竹胶板性能优异,其静曲强度及其弹性模量、吸水厚度膨胀率及胶合强度等物理力学性能均符合LY/T 1574-2000《混凝土模板用竹材胶合板》标准的B类竹材胶合板要求,与纯酚醛胶所制竹胶板的胶合性能相当,且对竹材浸胶量影响较小。HKLF添加量为40%时,竹胶板干状横向静曲强度和吸水厚度膨胀率不达标。因此,HKLF添加量为10%~30%的KPF作为竹胶板用胶黏剂是可行的。
採用羥甲基化堿木質素(HKLF)與酚醛樹脂(PF)複閤製備堿木質素-酚醛複閤膠黏劑(KPF),研究瞭HKLF添加量對KPF性能的影響,併分析其在竹膠闆中應用的可行性。結果錶明:HKLF添加量為10%~30%的KPF生產的竹膠闆性能優異,其靜麯彊度及其彈性模量、吸水厚度膨脹率及膠閤彊度等物理力學性能均符閤LY/T 1574-2000《混凝土模闆用竹材膠閤闆》標準的B類竹材膠閤闆要求,與純酚醛膠所製竹膠闆的膠閤性能相噹,且對竹材浸膠量影響較小。HKLF添加量為40%時,竹膠闆榦狀橫嚮靜麯彊度和吸水厚度膨脹率不達標。因此,HKLF添加量為10%~30%的KPF作為竹膠闆用膠黏劑是可行的。
채용간갑기화감목질소(HKLF)여분철수지(PF)복합제비감목질소-분철복합효점제(KPF),연구료HKLF첨가량대KPF성능적영향,병분석기재죽효판중응용적가행성。결과표명:HKLF첨가량위10%~30%적KPF생산적죽효판성능우이,기정곡강도급기탄성모량、흡수후도팽창솔급효합강도등물리역학성능균부합LY/T 1574-2000《혼응토모판용죽재효합판》표준적B류죽재효합판요구,여순분철효소제죽효판적효합성능상당,차대죽재침효량영향교소。HKLF첨가량위40%시,죽효판간상횡향정곡강도화흡수후도팽창솔불체표。인차,HKLF첨가량위10%~30%적KPF작위죽효판용효점제시가행적。
The lignin-phenol-formaldehyde resin adhesive(KPF) was prepared by blending phenol-formaldehyde resin(PF) with alkali lignin modified by hydroxymethylation(HKLF).Effect of amount of lignin on performance of bamboo plywood was studied.The feasibility of alkali lignin-phenol-formaldehyde resin used in bamboo plywood was analyzed.The results showed that mechanical properties of bamboo plywood,such as modulus of rupture,modulus of elasticity,thickness swelling rate and bonding quality,met the standards of LY/T 1574-2000,when dose of hydroxymethylated lignin was 10 % to 30 %.Performance of bamboo plywood with KPF is almost the same as that of other similar products with PF.However,when dose of hydroxymethylated lignin was 40 %,modulus of rupture and thickness swelling rate did not meet standards.Therefore,KPF can be applied to bamboo plywood when dose of hydroxymethylated lignin was 10 % to 30 %.