科学技术与工程
科學技術與工程
과학기술여공정
SCIENCE TECHNOLOGY AND ENGINEERING
2009年
9期
2362-2365,2383
,共5页
铌酸钴%光电极%可见光%光电化学
鈮痠鈷%光電極%可見光%光電化學
니산고%광전겁%가견광%광전화학
cobalt nitrate%photoelectrode%visible light%photoelectrochemistry
报道了可见光催化材料CoNb2O6的合成及其光电化学性质.材料的合成方法采用溶胶-凝胶法.X-射线衍射(XRD)及紫外-可见漫发射光谱(DRS)表征结果表明,所合成的材料是正交相结构的CoNb2O6晶体,具有较好的可见光吸收性能.采用线性扫描伏安(LSV)法和瞬时电流曲线(i-t)等手段对所材料的电化学性质进行了研究,发现在可见光照射下电极上有较强的光电流产生,表明该材料具有较好的可见光电转换性能.
報道瞭可見光催化材料CoNb2O6的閤成及其光電化學性質.材料的閤成方法採用溶膠-凝膠法.X-射線衍射(XRD)及紫外-可見漫髮射光譜(DRS)錶徵結果錶明,所閤成的材料是正交相結構的CoNb2O6晶體,具有較好的可見光吸收性能.採用線性掃描伏安(LSV)法和瞬時電流麯線(i-t)等手段對所材料的電化學性質進行瞭研究,髮現在可見光照射下電極上有較彊的光電流產生,錶明該材料具有較好的可見光電轉換性能.
보도료가견광최화재료CoNb2O6적합성급기광전화학성질.재료적합성방법채용용효-응효법.X-사선연사(XRD)급자외-가견만발사광보(DRS)표정결과표명,소합성적재료시정교상결구적CoNb2O6정체,구유교호적가견광흡수성능.채용선성소묘복안(LSV)법화순시전류곡선(i-t)등수단대소재료적전화학성질진행료연구,발현재가견광조사하전겁상유교강적광전유산생,표명해재료구유교호적가견광전전환성능.
The synthesis and photoelectrochemical properties of visible-light-responsive photocatalytic CoNb2O6 materials were reported.The materials were prepared by using the sol-gel method.X-ray diffraction (XRD) and diffuse reflectance spectroscope (DRS) characterization data suggested that the CoNb2O6 material has an orthorhombic structure with a good visible-light absorption property.The photoelectrochemical properties evaluated using the linear sweep voltammetry (LSV) method and the current-time (i-t) curves showed an intensive photocurrent under visible-light (λ>420 nm) irradiation from the materials used as thin film electrode,suggesting that the materials have a good photo-to-current conversion property.