无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2012年
7期
1506-1512
,共7页
徐瑞%钟本和%郭孝东%唐艳%唐红%方为茂%刘恒
徐瑞%鐘本和%郭孝東%唐豔%唐紅%方為茂%劉恆
서서%종본화%곽효동%당염%당홍%방위무%류항
LiFePO4/C%流变相法%锂源%高倍率
LiFePO4/C%流變相法%鋰源%高倍率
LiFePO4/C%류변상법%리원%고배솔
LiFePO4/C%rheological phase method%lithium sources%high rate
以月桂酸为碳源和表面活性剂,氢氧化锂、碳酸锂和醋酸锂为锂源,采用流变相法制备KiFePO4/C复合材料.运用X射线衍射(XRD)、扫描电子显微镜(SEM)、粒度分析、恒流充放电测试、循环伏安以及交流阻抗测试等方法对复合材料进行表征.结果表明,不同的锂源对LiFePO4/C复合材料的结构和电化学性能均有很大影响,以氢氧化锂为锂源合成的LiFePO4/C材料展示出最佳的循环性能和倍率性能.该材料在0.1C下放电比容量为153.4 mAh·g-1,在大倍率10C下,容量保持率仍可达76%,甚至10C下循环800次后,容量衰减率仅有4%,SEM结果显示该材料具有较小的粒径(~200 nm),且分布集中,有效提高了电子迁移速率,从而改进了LiFePO4/C的倍率性能.
以月桂痠為碳源和錶麵活性劑,氫氧化鋰、碳痠鋰和醋痠鋰為鋰源,採用流變相法製備KiFePO4/C複閤材料.運用X射線衍射(XRD)、掃描電子顯微鏡(SEM)、粒度分析、恆流充放電測試、循環伏安以及交流阻抗測試等方法對複閤材料進行錶徵.結果錶明,不同的鋰源對LiFePO4/C複閤材料的結構和電化學性能均有很大影響,以氫氧化鋰為鋰源閤成的LiFePO4/C材料展示齣最佳的循環性能和倍率性能.該材料在0.1C下放電比容量為153.4 mAh·g-1,在大倍率10C下,容量保持率仍可達76%,甚至10C下循環800次後,容量衰減率僅有4%,SEM結果顯示該材料具有較小的粒徑(~200 nm),且分佈集中,有效提高瞭電子遷移速率,從而改進瞭LiFePO4/C的倍率性能.
이월계산위탄원화표면활성제,경양화리、탄산리화작산리위리원,채용류변상법제비KiFePO4/C복합재료.운용X사선연사(XRD)、소묘전자현미경(SEM)、립도분석、항류충방전측시、순배복안이급교류조항측시등방법대복합재료진행표정.결과표명,불동적리원대LiFePO4/C복합재료적결구화전화학성능균유흔대영향,이경양화리위리원합성적LiFePO4/C재료전시출최가적순배성능화배솔성능.해재료재0.1C하방전비용량위153.4 mAh·g-1,재대배솔10C하,용량보지솔잉가체76%,심지10C하순배800차후,용량쇠감솔부유4%,SEM결과현시해재료구유교소적립경(~200 nm),차분포집중,유효제고료전자천이속솔,종이개진료LiFePO4/C적배솔성능.
LiFePO4/C was synthesized by rheological phase method (a soft chemical method) using lauric acid as the carbon source and surfactant,lithium hydroxide,lithium carbonate and lithium acetate as the lithium source.The materials were characterized by X-ray diffraction (XRD),scanning electron microscopy (SEM),particle size analysis,constant-current charge/discharge test,cyclic voltammetry (CV) and electrochemical impedance spectra (EIS).The results show that the effect of the lithium source on the morphology and the electrochemical performance of LiFePO4/C composites is great.The LiFePO4/C sample with lithium hydroxide as the lithium source exhibits the best cycling performance and rate capability.It shows a specific capacity of 153.4 mAh·g-1 at 0.1 C,a capacity retention rate of 76% at high current density of 10 C,and a lossing rate of 4% at 10C after 800 cycles.The excellent performance of this LiFePO4/C is attributed to the smaller size (~200 nm) and the narrower particle size distribution.