高校化学工程学报
高校化學工程學報
고교화학공정학보
JOURNAL OF CHEMICAL ENGINEERING OF CHINESE UNIVERSITIES
2010年
1期
150-155
,共6页
薛通%薛源%杨凤林%付志敏%柳丽芬%王婵婵
薛通%薛源%楊鳳林%付誌敏%柳麗芬%王嬋嬋
설통%설원%양봉림%부지민%류려분%왕선선
短程硝化反硝化%污泥厌氧水解%实际城市污水%低C/N比
短程硝化反硝化%汙泥厭氧水解%實際城市汙水%低C/N比
단정초화반초화%오니염양수해%실제성시오수%저C/N비
shortcut nitrification-denitrification%sludge hydrolysis%actual municipal wastewater%low C/N ratio
为处理低碳氮比城市污水,在30~35℃、不调节pH值(7.01~8.33)的条件下,通过人为添加氨氮控制游离氨浓度(25 mg·L~(-1)),在SBR中6 d内成功启动了短程硝化反硝化.对比实验结果表明,短程硝化反硝化在处理低C/N比城市污水时的总氮脱除效果要优于传统的全程硝化反硝化,当反应器运行稳定后,溶解氧的浓度和高游离氨不再是影响NO_2~--N浓度累积的主要因素,NO_2~--N/NO_x~--N始终保持在80%以上.为了进一步提高短程硝化反硝化的脱氮效率,利用污泥厌氧水解产物替代10%进水,为反硝化阶段提供附加的部分碳源,两工艺联合后处理效果良好,出水TN平均浓度和去除率分别为13.39 mg·L~(-1)和74.9%,出水水质符合排放标准的要求.
為處理低碳氮比城市汙水,在30~35℃、不調節pH值(7.01~8.33)的條件下,通過人為添加氨氮控製遊離氨濃度(25 mg·L~(-1)),在SBR中6 d內成功啟動瞭短程硝化反硝化.對比實驗結果錶明,短程硝化反硝化在處理低C/N比城市汙水時的總氮脫除效果要優于傳統的全程硝化反硝化,噹反應器運行穩定後,溶解氧的濃度和高遊離氨不再是影響NO_2~--N濃度纍積的主要因素,NO_2~--N/NO_x~--N始終保持在80%以上.為瞭進一步提高短程硝化反硝化的脫氮效率,利用汙泥厭氧水解產物替代10%進水,為反硝化階段提供附加的部分碳源,兩工藝聯閤後處理效果良好,齣水TN平均濃度和去除率分彆為13.39 mg·L~(-1)和74.9%,齣水水質符閤排放標準的要求.
위처리저탄담비성시오수,재30~35℃、불조절pH치(7.01~8.33)적조건하,통과인위첨가안담공제유리안농도(25 mg·L~(-1)),재SBR중6 d내성공계동료단정초화반초화.대비실험결과표명,단정초화반초화재처리저C/N비성시오수시적총담탈제효과요우우전통적전정초화반초화,당반응기운행은정후,용해양적농도화고유리안불재시영향NO_2~--N농도루적적주요인소,NO_2~--N/NO_x~--N시종보지재80%이상.위료진일보제고단정초화반초화적탈담효솔,이용오니염양수해산물체대10%진수,위반초화계단제공부가적부분탄원,량공예연합후처리효과량호,출수TN평균농도화거제솔분별위13.39 mg·L~(-1)화74.9%,출수수질부합배방표준적요구.
In order to achieve nitrogen removal in treating municipal wastewater with low C/N ratio, a shortcut nitrification-denitrification process was successfully developed in a sequencing batch reactor (SBR) in 6 days with the operation conditions of working at 30~35℃, without pH control (7.01~8.33) and maintaining a high concentration of free ammonia (FA, 25 mg·L~(-1)) by adding NH4+-N. The experiment results show that the total nitrogen removal efficiency of shortcut nitrification-denitrification is superior to that of the traditional nitrification-denitrification in treating municipal wastewater with low C/N ratio. It was also found that dissolved oxygen (DO) and FA do not affect accumulation of NO_2~--N when the operation is stabilized, and the NO_2~--N/NO_x~--N ratio could be maintained over 80%. In order to enhance the nitrogen removal efficiency of the shortcut nitrification-denitrification, 10% of SBR influent is replaced with the products of sludge anaerobic hydrolysis for supplying extra part of the carbon sources for denitrification. The total nitrogen removal efficiency of the combined process is 74.9%. The total nitrogen concentration in the effluent is 13.39 mg·L~(-1), which meets the quality requirement of the discharge standards.