CAJ | 학술논문

采用示差扫描量热仪(DSC)研究了具有生物相容性及可降解性P(BHB-CL)超支化共聚酯的非等温熔融结晶过程,分别采用Avrami方程、Ozawa方程和Mo方程对P(BHB-CL)共聚酯的非等温动力学数据进行比较分析,计算了相关的非等温结晶动力学参数,并利用Kissinger方程计算其非等温结晶活化能.结果表明,Mo方程更适合描述P(BHB-CL)共聚酯的非等温结晶过程.
채용시차소묘량열의(DSC)연구료구유생물상용성급가강해성P(BHB-CL)초지화공취지적비등온용융결정과정,분별채용Avrami방정、Ozawa방정화Mo방정대P(BHB-CL)공취지적비등온동역학수거진행비교분석,계산료상관적비등온결정동역학삼수,병이용Kissinger방정계산기비등온결정활화능.결과표명,Mo방정경괄합묘술P(BHB-CL)공취지적비등온결정과정.
The nonisothermal crystallization behavior of biocompatible and biodegradable polyester P(BHB-CL) was investigated via differential scanning calorimetry(DSC). Avrami equation, Ozawa approach, and Mo approach were adopted to study the nonisothermal crystallization of P(BHB-CL), and activation energy value of P(BHB-CL) was determined according to the Kissenger method. The results show that Mo approach can be successfully applied to analyze the nonisothermal crystallization process of P(BHB-CL).