无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2007年
8期
1429-1431
,共3页
高洪苓%林通%亢惠娟%陈雄斌
高洪苓%林通%亢惠娟%陳雄斌
고홍령%림통%항혜연%진웅빈
反-4-(4-氯苯乙烯基)吡啶%银配合物%晶体结构%三维网络
反-4-(4-氯苯乙烯基)吡啶%銀配閤物%晶體結構%三維網絡
반-4-(4-록분을희기)필정%은배합물%정체결구%삼유망락
(E)4-(4-chlorostyryl) pyridine%silver(I) complex%crystal structure%three-dimensional network
A silver(Ⅰ) complex [Ag(chlsp)2](CF3CO2), (chlsp=(E)-4-(4-chlorostyryl) pyridine), was synthesized by the reaction between AgCF3CO2 and chlsp in the anhydrous enthnol. The crystal structure of [Ag(chlsp)2](CF3CO2)was characterized by elemental analysis, IR and determined by using single crystal X-ray diffraction. The result shows that the complex crystallize in triclinic system, with space group P-1, a=0.109 7(2) nm, b=0.111 7(2) nm, c=0.117 2(2) nm, α=73.60(3)°, β=85.03(3)°, γ=81.82(3)°, V=0.136 2(4) nm3, Z=2. The moleculars are connected by Ag…Ag and Ag…Cl interactions, resulting in a three-dimensional network. CCDC: 631131.
