物理化学学报
物理化學學報
물이화학학보
ACTA PHYSICO-CHIMICA SINICA
2001年
3期
270-272
,共3页
李旦振%郑宜%傅贤智%刘平
李旦振%鄭宜%傅賢智%劉平
리단진%정의%부현지%류평
纳米二氧化钛%光催化氧化%微波%乙烯
納米二氧化鈦%光催化氧化%微波%乙烯
납미이양화태%광최화양화%미파%을희
采用微波法、混合加热法和常规加热法制备 /TiO2催化剂 ,运用 XRD、 BET、 DRS及 LRS光谱测定等技术对催化剂的结构进行了表征 ,并以光催化降解 C2H4为模型反应考察了不同制备方法对催化剂的光催化氧化反应性能的影响 .研究结果表明 ,微波法制备的 /TiO2催化剂的光催化氧化性能得到明显改善 ,对乙烯转化率为 80% ,而混合加热法和常规加热法制备的样品乙烯转化率分别为 58%和 41% .微波辐射制备的催化剂锐钛矿相含量高、比表面积大 ,光吸收阈值增大;并且拉曼散射光谱向低波数方向移动 ,有助于增加光致电子的跃迁几率 ,提高多相光催化过程的本征量子效率 .
採用微波法、混閤加熱法和常規加熱法製備 /TiO2催化劑 ,運用 XRD、 BET、 DRS及 LRS光譜測定等技術對催化劑的結構進行瞭錶徵 ,併以光催化降解 C2H4為模型反應攷察瞭不同製備方法對催化劑的光催化氧化反應性能的影響 .研究結果錶明 ,微波法製備的 /TiO2催化劑的光催化氧化性能得到明顯改善 ,對乙烯轉化率為 80% ,而混閤加熱法和常規加熱法製備的樣品乙烯轉化率分彆為 58%和 41% .微波輻射製備的催化劑銳鈦礦相含量高、比錶麵積大 ,光吸收閾值增大;併且拉曼散射光譜嚮低波數方嚮移動 ,有助于增加光緻電子的躍遷幾率 ,提高多相光催化過程的本徵量子效率 .
채용미파법、혼합가열법화상규가열법제비 /TiO2최화제 ,운용 XRD、 BET、 DRS급 LRS광보측정등기술대최화제적결구진행료표정 ,병이광최화강해 C2H4위모형반응고찰료불동제비방법대최화제적광최화양화반응성능적영향 .연구결과표명 ,미파법제비적 /TiO2최화제적광최화양화성능득도명현개선 ,대을희전화솔위 80% ,이혼합가열법화상규가열법제비적양품을희전화솔분별위 58%화 41% .미파복사제비적최화제예태광상함량고、비표면적대 ,광흡수역치증대;병차랍만산사광보향저파수방향이동 ,유조우증가광치전자적약천궤솔 ,제고다상광최화과정적본정양자효솔 .
/TiO2 catalysts were prepared by microwave,composite and conventional methods and characterized by X-ray diffraction (XRD),N2 sorption analysis applying BET method,UV-Vis diffuse reflection spectroscopy(DRS) and laser Raman spectrum.The effect of different preparation methods on photocatalytic oxidation of C2H4 in air stream was studied.The results showed that the photocatalytic activity was obviously increased by the microwave method.The conversion of ethylene was 80% contrast to those of composite and conventional methods being only 58% and 41% ,respectively.The catalyst by microwave method exhibited higher content of anatase,higher specific surface area,larger band gap.The Raman scattering shifted to low wave number direction helped to increase the transition probability of photon generated electrons and improved photoefficiency.