贵金属
貴金屬
귀금속
PRECIOUS METALS
2002年
4期
14-20,5
,共8页
衣宝廉%俞红梅%侯中军%林志银%张锦新%明平文%张华民
衣寶廉%俞紅梅%侯中軍%林誌銀%張錦新%明平文%張華民
의보렴%유홍매%후중군%림지은%장금신%명평문%장화민
质子交换膜燃料电池%PtRu/C%PtRu-HxWOy/C%CO%电催化剂%复合电极
質子交換膜燃料電池%PtRu/C%PtRu-HxWOy/C%CO%電催化劑%複閤電極
질자교환막연료전지%PtRu/C%PtRu-HxWOy/C%CO%전최화제%복합전겁
PEMFCs%PtRu/C%PtRu-HxWOy/C,%CO%Electrocatalysts%Cowmposite electrode
本文介绍了大连化学物理研究所燃料电池工程中心所研制的PtRu/C和PtRu-HxWOy/C两种抗CO催化剂的制备和表征结果,PtRu-HxWOy/C采用复合载体法制备.当以含CO的燃料操作时,所研制的抗CO催化剂制备电池的性能明显高于Pt/C制备的电池.开发了一种复合结构的抗CO电极,这种电极具有良好的抗CO能力.用这种结构的电极组装的5-kW电池组以甲醇重整气为燃料时表现出良好的性能.
本文介紹瞭大連化學物理研究所燃料電池工程中心所研製的PtRu/C和PtRu-HxWOy/C兩種抗CO催化劑的製備和錶徵結果,PtRu-HxWOy/C採用複閤載體法製備.噹以含CO的燃料操作時,所研製的抗CO催化劑製備電池的性能明顯高于Pt/C製備的電池.開髮瞭一種複閤結構的抗CO電極,這種電極具有良好的抗CO能力.用這種結構的電極組裝的5-kW電池組以甲醇重整氣為燃料時錶現齣良好的性能.
본문개소료대련화학물리연구소연료전지공정중심소연제적PtRu/C화PtRu-HxWOy/C량충항CO최화제적제비화표정결과,PtRu-HxWOy/C채용복합재체법제비.당이함CO적연료조작시,소연제적항CO최화제제비전지적성능명현고우Pt/C제비적전지.개발료일충복합결구적항CO전겁,저충전겁구유량호적항CO능력.용저충결구적전겁조장적5-kW전지조이갑순중정기위연료시표현출량호적성능.
CO tolerance electrocatalysts of PtRu/C and PtRu-HxWOy/C were prepared and characterized.A composite support method was applied to prepare PtRu-HxWOy/C.The performances of cell made of the CO tolerance catalysts were much higher than that of Pt/C when CO containing fuel was applied.A composite structure electrode was developed,and showed good CO tolerance.At last a 5-kW PEMFC stack equipped with the composite structure electrodes was operated with methanol reforming fuel,and showed good performance.