CAJ | 학술논문

综述了二硫代氨基甲酸盐类(DTCs)杀菌剂及其代谢物的残留分析研究现状,并对当前主要的残留分析方法如分光光度法、气相色谱法、液相色谱法及液相色谱-质谱联用技术和毛细管电泳法进行了较为详细的比较、分析,对DTCs类杀菌剂残留分析方法的未来发展进行了展望.衍生化液相色谱法虽然操作步骤较繁琐、耗时长,但结果稳定可靠,并能区分不同结构类型,是目前重点且被广泛采用的方法,而同时测定DTCs类杀菌剂母体及其代谢物的串联质谱方法将是今后进一步研究的热点课题.
종술료이류대안기갑산염류(DTCs)살균제급기대사물적잔류분석연구현상,병대당전주요적잔류분석방법여분광광도법、기상색보법、액상색보법급액상색보-질보련용기술화모세관전영법진행료교위상세적비교、분석,대DTCs류살균제잔류분석방법적미래발전진행료전망.연생화액상색보법수연조작보취교번쇄、모시장,단결과은정가고,병능구분불동결구류형,시목전중점차피엄범채용적방법,이동시측정DTCs류살균제모체급기대사물적천련질보방법장시금후진일보연구적열점과제.
The analysis methods of dithiocarbamates(DTCs) fungicide and their metabolites, including detailed discussion of individual analysis methods, such as spectrophotometry, gas chromatography, liquid chromatography, liquid chromatography-mass spectrometry and micellar electrokinetic chromatography, etc. were reviewed. The prospects of application on the residue analysis of DTCs were predicted. Currently, high performance liquid chromatography (HPLC) determination with derivation is becoming the most applicable method, with its time-consuming, in several steps but good precision and reliability, plus with resolution for 3 different types of DTCs. It' s expected that the simultaneous determination of dithiocarbamate fungicides matrix and their metabolites with tandem mass spectroscopy would be an active hotspot in this field.