CAJ | 학술논문

利用苯乙炔或丙炔醇与[Mo(CO)2(η-C5H4R1)]2[R1=C(O)Me,C(O)OEt,C(O)Ph]的反应合成了6个新的炔烃配位的双钼化合物[Mo(CO)2(η5-C5H4R1)]2(μ-η2,η2-(CH=CR2)[R1=C(O)Me,R2=Ph,1;R1=C(O)OEt,R2=Ph,2;R1=C(O)Ph,R2=Ph,3;R1=C(O)Me,R2=CH2OH,4;R1=C(O)OEt,R2=CH 2OH,5;R1=C(O)Ph,R2=CH2OH,6],并对这些化合物进行了C/H元素分析,IR,1H NMR等表征.晶体X射线衍射分析结果表明,化合物1属单斜晶系,P21(#4)空间群,晶胞参数a=0.767 1(2)nm,b=0.836 5(2)nm,c=1.830 8(3)nm,β=98.34(1)°,V=1.162 3(5)nm3,Z=2,Dc=1.772 g·cm-3,F(000)=616,R=0.041,Rw=0.045.
이용분을결혹병결순여[Mo(CO)2(η-C5H4R1)]2[R1=C(O)Me,C(O)OEt,C(O)Ph]적반응합성료6개신적결경배위적쌍목화합물[Mo(CO)2(η5-C5H4R1)]2(μ-η2,η2-(CH=CR2)[R1=C(O)Me,R2=Ph,1;R1=C(O)OEt,R2=Ph,2;R1=C(O)Ph,R2=Ph,3;R1=C(O)Me,R2=CH2OH,4;R1=C(O)OEt,R2=CH 2OH,5;R1=C(O)Ph,R2=CH2OH,6],병대저사화합물진행료C/H원소분석,IR,1H NMR등표정.정체X사선연사분석결과표명,화합물1속단사정계,P21(#4)공간군,정포삼수a=0.767 1(2)nm,b=0.836 5(2)nm,c=1.830 8(3)nm,β=98.34(1)°,V=1.162 3(5)nm3,Z=2,Dc=1.772 g·cm-3,F(000)=616,R=0.041,Rw=0.045.