中国科学B辑(英文版)
中國科學B輯(英文版)
중국과학B집(영문판)
SCIENCE IN CHINA(SCIENTIA SINICA)
2002年
5期
503-508
,共6页
韦永莉%宋连卿%侯红卫%樊耀亭
韋永莉%宋連卿%侯紅衛%樊耀亭
위영리%송련경%후홍위%번요정
coordination polymer%synthesis%three-dimensional cage-like structure%magnetic property
A new organic-inorganic hetero-coordination polymer with three different kinds of ligands n is synthesized in the extremely mild condition. The X-ray diffraction reveals that the title polymer has a highly tactic three-dimensional cagelike supramolecular structure. Although the coordination bond makes it a one-dimension chain, the hydrogen bond plays an important role in the formation of 3-D supramolecular frameworks. The determination of magnetic properties has been carried out, and shows that it behaves weak antiferromagnetic property with J(4,4′-bpy) = -3.8 cm-1.
