中国化学工程学报(英文版)
中國化學工程學報(英文版)
중국화학공정학보(영문판)
CHINESE JOURNAL OF CHEMICAL ENGINEERING
2003年
6期
677-680
,共4页
屈玲%佟大明%吕志平%萧墉壮%窦涛
屈玲%佟大明%呂誌平%蕭墉壯%竇濤
굴령%동대명%려지평%소용장%두도
MCM-41%host-guest polymerization%polystyrene%glass transition temperature
The polymerization of styrene in the media of MCM-41 is carried out by means of host-guest polymerization of styrene in MCM-41 mesoporoas material with the aim to investigate the effects of interface and confinement of MCM-41 on host-guest interactions. Detailed physical properties of the mesoporous MCM-41 material containing polystyrene is characterized by XRD(X-ray diffraction), FT-IR(Fourier transform infrared), TGA(thermal gravimetric analysis), and nitrogen adsorption-desorption isotherms. We also find a great increase in the glass transition temperature of guest polystyrene influenced by the confined geometry of the host by differential scanning calorimetry (DSC).