漳州师范学院学报（自然科学版）
漳州師範學院學報（自然科學版）
장주사범학원학보（자연과학판）
JOURNAL OF ZHANGZHOU TEACHERS COLLEGE(NATURAL SCIENCE EDITION)
2010年
2期
97-101
,共5页
姚忠亮%林榕光%代义强%庄焱
姚忠亮%林榕光%代義彊%莊焱
요충량%림용광%대의강%장염
瓜环%单晶X-射线衍射%阴离子
瓜環%單晶X-射線衍射%陰離子
과배%단정X-사선연사%음리자
cucurbituriis%single crystal X-ray diffraction%anions
合成了瓜环与氯化锶及间苯二酚形成的化合物,其结构为单晶X-射线分析方法所确定.晶体属于正交晶系,空间群为P2(1)2(1)2,其中α=15.658(3)(A),b=11.522(2)(A),c=15.031(3)(A),Mr=1481.28.V=2711.6(8)A3,Z=4.Dc=1.814 g/cm3,μ=2.172,F(000)=1520,R=0.0627,wR=0.1710.在此化合物的结构中,主体分子瓜环的空腔内包有一个氯阴离子.
閤成瞭瓜環與氯化鍶及間苯二酚形成的化閤物,其結構為單晶X-射線分析方法所確定.晶體屬于正交晶繫,空間群為P2(1)2(1)2,其中α=15.658(3)(A),b=11.522(2)(A),c=15.031(3)(A),Mr=1481.28.V=2711.6(8)A3,Z=4.Dc=1.814 g/cm3,μ=2.172,F(000)=1520,R=0.0627,wR=0.1710.在此化閤物的結構中,主體分子瓜環的空腔內包有一箇氯陰離子.
합성료과배여록화송급간분이분형성적화합물,기결구위단정X-사선분석방법소학정.정체속우정교정계,공간군위P2(1)2(1)2,기중α=15.658(3)(A),b=11.522(2)(A),c=15.031(3)(A),Mr=1481.28.V=2711.6(8)A3,Z=4.Dc=1.814 g/cm3,μ=2.172,F(000)=1520,R=0.0627,wR=0.1710.재차화합물적결구중,주체분자과배적공강내포유일개록음리자.
The title compound[Sr2(C30H30N20O10)(H2O)4Cl]Cl·[C6H4(OH)2]2·6H2O was synthesized and characterized by single-crystal X-ray diffraction.The crystal belongs to the Orthorhombic system,space group P2(1)2(1)2 with α = 15.658(3),b = 11.522(2),c = 15.031(3)(A),Mr = 1481.28,V = 2711.6(8)(A)3,Z = 4,Dc = 1.814 g/cm3,μ = 2.172,F(000)= 1520.R = 0.0627 and wR = 0.1710 for 2491 observed reflections(1 >2 σ(I)).The crystal structure of the compound show a chlorine anion was encapsulated in cucurbit[5]uril to form a closed molecular capsule.
