东南大学学报(自然科学版)
東南大學學報(自然科學版)
동남대학학보(자연과학판)
JOURNAL OF SOUTHEAST UNIVERSITY
2009年
5期
913-917
,共5页
曹罚君%高飞%陈敏华%陈云飞
曹罰君%高飛%陳敏華%陳雲飛
조벌군%고비%진민화%진운비
微管%等效电阻特性%电极极化%离子电流
微管%等效電阻特性%電極極化%離子電流
미관%등효전조특성%전겁겁화%리자전류
microtube%equivalent resistance characteristics%electric polarization%ionic current
搭建测量微米级管道内溶液电阻的实验平台,研究了直径在50~300 μm玻璃管道内溶液的等效电阻,建立了在直流小电压作用下,微管内溶液的等效电阻与外加电压的相互关系,并对实验中的误差因素进行了分析.结果表明:在一定的电压范围内,微管内溶液的等效电阻与施加在两端的电压成非线性关系.在电压比较小的初始阶段,随着电压值的增大,微管的等效电阻值迅速减少;当电压增大到临界值(4~6 V)时,等效电阻的变化量减小,最后趋于一定的阻值,该阻值近似为对应本体溶液的电阻值.研究结果表明在电压较小的初始阶段,电解及电极极化作用主导微管等效电阻,随着电压的增大,由于离子电流的增加,这种影响会迅速减少.
搭建測量微米級管道內溶液電阻的實驗平檯,研究瞭直徑在50~300 μm玻璃管道內溶液的等效電阻,建立瞭在直流小電壓作用下,微管內溶液的等效電阻與外加電壓的相互關繫,併對實驗中的誤差因素進行瞭分析.結果錶明:在一定的電壓範圍內,微管內溶液的等效電阻與施加在兩耑的電壓成非線性關繫.在電壓比較小的初始階段,隨著電壓值的增大,微管的等效電阻值迅速減少;噹電壓增大到臨界值(4~6 V)時,等效電阻的變化量減小,最後趨于一定的阻值,該阻值近似為對應本體溶液的電阻值.研究結果錶明在電壓較小的初始階段,電解及電極極化作用主導微管等效電阻,隨著電壓的增大,由于離子電流的增加,這種影響會迅速減少.
탑건측량미미급관도내용액전조적실험평태,연구료직경재50~300 μm파리관도내용액적등효전조,건립료재직류소전압작용하,미관내용액적등효전조여외가전압적상호관계,병대실험중적오차인소진행료분석.결과표명:재일정적전압범위내,미관내용액적등효전조여시가재량단적전압성비선성관계.재전압비교소적초시계단,수착전압치적증대,미관적등효전조치신속감소;당전압증대도림계치(4~6 V)시,등효전조적변화량감소,최후추우일정적조치,해조치근사위대응본체용액적전조치.연구결과표명재전압교소적초시계단,전해급전겁겁화작용주도미관등효전조,수착전압적증대,유우리자전류적증가,저충영향회신속감소.
A test rig was set up to measure the equivalent resistance of the solution in microtubes with diameters ranging from 50 to 300 μm. The relationship between the equivalent resistance and the direct voltage applied on the two ends of the microtube was built up, and the error was analyzed. The experimental results show that the relationship between the value of the equivalent resistance and the voltage is nonlinear. The equivalent resistance decreases rapidly as the applied voltage increases in a relatively small range. When the voltage exceeds a critical value (4 to 6 V) , the decrease of resistance is reduced and finally the equivalent resistance approximately equals the resistance of the corresponding bulk solution. It is believed that the electrolysis and the electric polarization have important influences on the equivalent resistance of the solution in microtubes when voltage is small. At high voltages, the influences decrease quickly because of the relatively large ionic current.